O-Phenylene phosphorochloridate

Fu H, Li ZL, Zhao YF et al (1999) Oligomerization of N,0-bis(trimethylsilyl)-alpha-amino acids into peptides mediated by o-phenylene phosphorochloridate. J Am Chem Soc... 

Phase-transfer catalysts, 220, 221,305-306 Phenanthrenes, 319, 320 9-Phenanthrol, 431 Phenol annelation, 272 Phenoxysulfonyl azide, 377-378 Phenylacetaldehyde, 217 Phenylacetylene, 7 2 (S)-3-Phenyl-1-butene, 36 Phenyl chlorothionocarbonate, 306-307 Phenyl cyanate, 307-308 Phenyldiazomethane, 308 o-Phenylene phosphorochloridate, 91-92 o-Phenylglydne methyl ester, 308 Phenyl isocyanate, 309 Phenyl isocyanide, 309-310 Phenyl iso thiocyanate, 122 Phenyllithium, 5... 

The reaction between the cyclic phosphorochloridate (109) and a strictly equimolar amount of water yields o-phenylene hydrogen phosphate (110) in the presence of excess water, both (109) and (110) afford the acyclic pho.sphate (112). On the other hand, the cyclic esters and amide (111) with one mole of water each yield the corresponding (113)... 

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