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Nucleophilic Additions to Sugar Lactones Followed by Lactol Reductions

9 Nucleophilic Additions to Sugar Lactones Followed BY Lactol Reductions [Pg.299]

SCHEME 7.44 Reactions of sulfur ylides with lactols. [Pg.299]

FIGURE 7.15 Example of C-glycosides from sugar lactones. [Pg.300]

Related examples utilizing aryllithium reagents were reported by Czernecki and Ville [156] and Krohn et al. [157]. [Pg.301]

SCHEME 7.48 Lactol reduction with sodium cyanoborohydride. [Pg.301]



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Additives sugars

Lactols Lactone

Lactones lactols

Lactones reduction

Nucleophilic addition to

Nucleophilic additions by

Reduction to lactones

Reductive addition

Sugars reduction

To lactone

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