Nuclearity, changes decrease

NOE Nuclear Overhauser effect, change of signal intensities (integrals) dining decoupling experiments decreasing with spatial distance of nuclei... 

The very slight differences that do exist among these elements are due to small changes in size brought about by increase of nuclear charge. The separation of the lanthanide elements from each other is based upon clever exploitation of these slight differences in properties. Table 23-1 shows a comparison of some of the properties of the various lanthanide elements. As can be seen, +3 is the common oxidation number and is most characteristic of the chemistry of these elements. Another thing to note is the steady decrease in... 

The properties of such materials are not measurably altered until subjected to doses in excess of a million rads. At these higher doses, the principal changes are due to chem decompn which, with very few exceptions, resnlt in a decrease in sensitivity to mechanical stimulus and also in a dimunition of expl output. The radiation doses normally encountered in neutron activation procedures range from a few rads for 14 MeV fast neutron activation to several thousand rads for thermal neutron activations in a nuclear reactor. Thus, such doses are well under the limit at which measurable changes can occur... 

The relative change of the mean-square nuclear radius in going from the excited to the ground state, A r )/ r ), is positive for u. An increase in observed isomer shifts S therefore reflects an increase of the s-electron density at the Ru nucleus caused by either an increase in the number of s-valence electrons or a decrease in the number of shielding electrons, preferentially of d-character. 

Renal Effects. The characteristics of early or acute lead-induced nephropathy in humans include nuclear inclusion bodies, mitochondrial changes, and cytomegaly of the proximal tubular epithelial cells dysfunction of the proximal tubules (Fanconi s syndrome) manifested as aminoaciduria, glucosuria, and phosphaturia with hypophosphatemia and increased sodium and decreased uric acid excretion. These effects appear to be reversible. Characteristics of chronic lead nephropathy include progressive interstitial fibrosis, dilation of tubules and atrophy or hyperplasia of the tubular epithelial cells, and few or no nuclear inclusion bodies, reduction in glomerular filtration rate, and azotemia. These effects are irreversible. The acute form is reported in lead-intoxicated children, whose primary exposure is via the oral route, and sometimes in lead workers. The chronic form is reported mainly in lead workers, whose primary exposure is via inhalation. Animal studies provide evidence of nephropathy similar to that which occurs in humans, particularly the acute form (see Section 2.2.3.2). 

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