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Nonadiabatic solvent effects, electron-transfer electronic coupling

Figure 9.6 Pressure-effect on rates of some self-exchange electron-transfer reactions between metal ions comparison of observed volumes of activation with values calculated from classical Marcus theory for adiabatic reactions. The plot shows calculated and observed AP values (cm mol ) at mid-range of pressure (100 MPa, except 70 MPa for Fe(H20)g ) for adiabatic (filled symbols) and nonadiabatic (open circles) self-exchange in couples with rigid ligands. Solvents (o, ) water ( ) CD3CN (A) (CD3)2CO (V) CD3OD. Key (A,B) (C,D) Cu(dmp)2 (E-G) Ru(hfac)j (H) Fe(C5H5)2 (I-K) Mn(CN-t-Bu)g ... Figure 9.6 Pressure-effect on rates of some self-exchange electron-transfer reactions between metal ions comparison of observed volumes of activation with values calculated from classical Marcus theory for adiabatic reactions. The plot shows calculated and observed AP values (cm mol ) at mid-range of pressure (100 MPa, except 70 MPa for Fe(H20)g ) for adiabatic (filled symbols) and nonadiabatic (open circles) self-exchange in couples with rigid ligands. Solvents (o, ) water ( ) CD3CN (A) (CD3)2CO (V) CD3OD. Key (A,B) (C,D) Cu(dmp)2 (E-G) Ru(hfac)j (H) Fe(C5H5)2 (I-K) Mn(CN-t-Bu)g ...
See other pages where Nonadiabatic solvent effects, electron-transfer electronic coupling is mentioned: [Pg.485]    [Pg.15]    [Pg.4]    [Pg.341]    [Pg.462]    [Pg.333]    [Pg.24]   
See also in sourсe #XX -- [ Pg.530 , Pg.531 , Pg.532 ]



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Effective coupling

Electron coupled

Electron coupled transfers

Electron coupling

Electron solvents

Electron transfer coupling

Electron transfer effect

Electron transfer electronic coupling

Electron transfer solvent

Electron transfer solvent effect

Electron-transfer . nonadiabatic solvent

Electron-transfer . nonadiabatic solvent electronic coupling

Electronic coupling

Electronic nonadiabaticity

Nonadiabatic coupling

Nonadiabatic coupling effects

Nonadiabatic electron transfer

Solvent transfer

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