Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Non-statistical dynamics

EXAMPLES OF ORGANIC REACTIONS WITH NON-STATISTICAL DYNAMICS... [Pg.514]

H0-CH3-F] HO + CH3F decomposition MP2/6-3H-G- Non-reaction path and non-statistical dynamics [122]... [Pg.416]

Various explanations have been given such as stepwise cleavage of the two C-N bonds with concerted backside displacement of the nitrogen molecule by the carbon radical and, intriguingly, conservation of momentum upon loss of dinitrogen that results in the double inversion product. This latter explanation has been pursued by Carpenter who has championed non-statistical dynamics as an explanation for many stereochemical pathways in thermal reactions. ... [Pg.68]

Alternatively, Carpenter s non-statistical dynamics argument would suggest that the depyramidalization of Cl with appropriate twisting motions in the ring opening generates a species whose momentum carries it on to the inverted product. ... [Pg.197]

See other pages where Non-statistical dynamics is mentioned: [Pg.222]    [Pg.444]   
See also in sourсe #XX -- [ Pg.68 , Pg.197 ]



SEARCH



Examples of Organic Reactions With Non-Statistical Dynamics

Non-statistical

© 2024 chempedia.info