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Nitryl perchlorate—

Nitrogen oxides and their derivatives displace CIO2 to form nitrosyl and nitryl perchlorates. These and other reactions are summarized in the scheme below. [Pg.850]

Nitryl Perchlorate (Nitroxyl Perchlorate). N02C104, mw 145.47, white cryst mp, decomps rapidly at 120° deflagrates on rapid heating Can be prepd by the action of cone nitric acid on perchloric acid ... [Pg.348]

Nitryl perchlorate reacts with organic matter with a violence ranging from slight explns to sharp detonations accompanied by fire. Incidents have been reported with acet, benz eth (Ref 2)... [Pg.348]

Thepnal Decomposition. Workers at the Hebrew Univ, Israel found that the thermal decompn of nitrosyl perchlorate at 100-140° results in an equilibrium being established with nitryl perchlorate and the decompn prods of both compds (nitronium). N dioxide, Cl dioxide, and O were found to be the final decompn prods isolated (Ref 6)... [Pg.640]

Nitryl Perchlorate (Nitroxyl Perchlorate, Ni-tronium Perchlorate). N02C104, mw 161.45, OB +29.7% colorl monoclinic hygr ciysts mp decomps above 135° without explg CA Registry No 17495-81-7 1... [Pg.640]

The medium impact-sensitivity of this solid propellant component is greatly increased by co-crystallisation of certain impurities, notably nitryl perchlorate, potassium periodate and potassium permanganate [1]. The presence of certain minimum amounts of mono-, di, tri- or tetra-methylammonium perchlorates in the salt leads to a single step decomposition, at around 290°C for the monoderivative [2],... [Pg.1367]

The explosively unstable behaviour of stored nitronium perchlorate is attributed to the formation of small equilibrium concentrations of the isomeric covalent nitryl perchlorate ester (below). [Pg.1384]

Nitrosyl tetrafluorochlorate, 3985 Nitrous acid, 4435 Nitryl chloride, 4025 Nitryl fluoride, 4303 Nitryl hypochlorite, 4026 Nitryl hypofluorite, 4304 Nitryl perchlorate, 4029 Osmium hexafluoride, 4370 Osmium(VIII) oxide, 4858 Oxygen (Gas), 4831 Oxygen (Liquid), 4832 Oxygen difluoride, 4317 Ozone, 4846... [Pg.309]

NITRYL PERCHLORATE (NITRONIUM PERCHLORATE, NITROXYL PERCHLORATE),... [Pg.483]

Nitryl perchlorate was obtained by Gordon and Spinks [19] by mixing chlorine dioxide with ozone and nitrogen dioxide. Ingold [20] prepared it from nitrogen pentoxide and anhydrous perchloric add by the reactions ... [Pg.484]

Earlier Hantzsch et al. [21] thought the precipitate in question was nitracidium and hydronitracidium perchlorates (p. 13, Vol. I). However Ingold et al. [22] showed that Hantzsch s product is a mixture of perchloric acid monohydrate and nitryl perchlorate. [Pg.484]

Dioxygenyl tetrafluoroborate Organic materials Nitric acid Hydrocarbons Nitryl perchlorate Organic solvents Oxygen (Liquid) Hydrocarbons Ozone Aromatic compounds, or Benzene, etc. Ozone Aromatic compounds, or Benzene, etc. Permanganic acid Organic materials Peroxodisulfuric acid Organic liquids Peroxomonosulfuric acid Aromatic compounds Silver perchlorate... [Pg.828]

Nitryl nitrate, see Dinitrogen pentaoxide, 4743 Nitryl perchlorate, 4023 Nonacarbonyldiiron, 3105 f Nonane, 3203... [Pg.2118]

Nitrogen dioxide, 4720 Nitrogen oxide, 4719 Nitrosyl chloride, 4017 Nitrosyl fluoride, 4296 Nitrosyl perchlorate, 4021 Nitrosyl tetrafluorochlorate, 3979 Nitrosylsulfuric acid, 4432 Nitrous acid, 4429 Nitryl chloride, 4019 Nitryl fluoride, 4297 Nitryl hypochlorite, 4020 Nitryl hypofluorite, 4298 Nitryl perchlorate, 4023 Osmium hexafluoride, 4364 Osmium(VIII) oxide, 4852 Oxygen difluoride, 4311 Oxygen (Gas), 4825 Oxygen (Liquid), 4826 Ozone, 4840... [Pg.2502]

Incompatible with CrO, (nitric + acetic acid), NOCl, nitryl perchlorate, permonosulfuric acid, NaOBr, (sulfuric acid + potassium dichromate), (thio-diglycol + hydrogen peroxide), trichloromelamine, air, HNO3, chloroform, and H2SO4. To fight fire, use CO2, dr chemical, alcohol foam. Used in production of drugs of abuse. [Pg.10]

Nitryl perchlorate (nitronium perchlorate, nitroxyl pcrchloru e) 483... [Pg.346]

See Halogens, or Interhalogens, above Chromy 1 chloride Organic solvents Fluorine nitrate Organic materials Hydrogen peroxide Diethyl ether lodine(Vll) oxide Diethyl ether Lithium perchlorate Diethyl ether Nitric acid Diethyl ether Nitrosyl perchlorate Organic materials Nitryl perchlorate Organic solvents Ozone Diethyl ether... [Pg.564]

See other pages where Nitryl perchlorate— is mentioned: [Pg.753]    [Pg.1385]    [Pg.288]    [Pg.269]    [Pg.224]    [Pg.646]    [Pg.1430]    [Pg.2481]    [Pg.753]    [Pg.1385]    [Pg.134]    [Pg.631]    [Pg.1081]    [Pg.1385]    [Pg.2037]    [Pg.2392]   
See also in sourсe #XX -- [ Pg.8 , Pg.165 ]



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