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Nitryl Azide

O2N—N3 was made under similar conditions from a nitryl salt and lithium azide, but was not isolated. In acetonitrile solution it decomposed above -10°C [63]. [Pg.74]

On warming up to room temperature, nitryl azide decomposes to dinitrogen oxide. [Pg.3051]

The reaction of nitronium hexafluoroantimonate with sodium azide at 223 K in carbon dioxide yields nitryl azide. ... [Pg.3051]

When equimolar amounts of a nitronium salt (NOjEFf) and an alkali-metal azide are mixed in an organic solvent (CCI4 or CHgCN) the resulting solution shows spectroscopic and chemical properties which are commensurate with the existence of nitryl azide, The pure compound was... [Pg.450]

With sodium azide, salts of secondary nitroparaffins rearrange to N-substituted amides (29). With SO2, primary or secondary nitroparaffins give imidodisulfonic acid salts (30). Potassium nitroform reacts quantitatively with nitryl chloride in ether to form tetranitromethane (31). [Pg.99]

Nitration of 1,2-dialkylvinyl azides with nitryl fluoroborate yields l-azido-2-nitroalkene (110), which spontaneously decomposes with loss of nitrogen to the dialkylfuroxan. Compound (110) is also formed on treatment of 1,2-dinitroalkenes with azide ion and from ... [Pg.423]

Olefin additions Bromine azide. Bromine chloride. Bromine (chlorine) dipyridine nitrate. N-Bromoacetamine. N-Bromoacetamide-DMSO-Water. N-Bromoacetamide-Hydrogen fluoride. n-Butyllithium. Dichloroketene. Dichloromethyl 2-chloromethyl ether. N,N-Dichlorourethane. Dichlorovinylene carbonate. Difluoramine. Ethyl azidoformate. Ethyl bromoacetate. Iodine azide. Iodine isocyanate. Iodine nitrate, lodobenzene dichloride. 1-lodoheptafluoropropane. Mercuric acetate. Nitrosyl chloride. Nitrosyl fluoride. Nitryl iodide. Rhodium trichloride. Silver fluoride. [Pg.242]

OLEFIN ADDITIONS Benzenesulfonyl azide. Chlorosulfonyl isocyanate. Chiom-ous chloride. Cyanamlde. Dichloroketene. Dinitrogen tetroxide-Iodine. Diphenyl-ketene. Ethoxyketene. Fluoroxytrifluoro-methane. Iodine. Iodine azide. Iodine isocyanate. Iodobenzene dichloride. Mercuric azide. Nitrosyl chloride. Nitrosyl fluoride. Nitryl iodide. Potassium f-but-oxide-Bromoform (dibromocarbene). [Pg.179]

SULFUROUS OXIDE (7446-09-5) SO, Noncombustible liquefied gas under pressure or liquid. Contact with air forms hydrogen chloride fumes. Violent reaction with water or steam, forming sulfurous acid, a medium-strong acid and corrosion hazard. Reacts violently with acetylene, acrolein, alcohols, aluminum powder alkali metals (i.e., potassium, sodium) amines, ammonia, bromine pentafluoride butadiene caustics, cesium acetylene carbide chlorates, chlorine trifluoride chromium powder copper or copper alloy powders chlorine, diethylzinc, fluorine, ethylene oxide lead dioxide lithium acetylene carbide diamino-, metal powders monolithium acetylide-ammonia nitryl chloride potassium acetylene carbide potassium acetylide, potassium chlorate rubidium carbide silver azide sodium acetylide staimous oxide. Decon oses in... [Pg.981]

See other pages where Nitryl Azide is mentioned: [Pg.443]    [Pg.3051]    [Pg.443]    [Pg.3050]    [Pg.32]    [Pg.74]    [Pg.443]    [Pg.3051]    [Pg.443]    [Pg.3050]    [Pg.32]    [Pg.74]    [Pg.163]    [Pg.273]    [Pg.1115]    [Pg.27]    [Pg.66]    [Pg.1118]    [Pg.163]    [Pg.163]    [Pg.659]    [Pg.89]    [Pg.94]    [Pg.587]    [Pg.627]    [Pg.783]    [Pg.940]    [Pg.976]    [Pg.981]    [Pg.981]    [Pg.982]    [Pg.76]    [Pg.93]   


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