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Nitrosyl chloride ferric

The next isolable intermediate in NO c reduction is hydroxylamine, and in this area Ryan s group has provided insightCyclic voltammograms of Fe(TPP) in a hydroxylamine solution show a one-electron reduction wave similar to the nitrosyl adduct, with complete conversion to a new species observable by both electrochemistry and visible absorbance measurements. Solution studies show that at low temperatures (-4°C), a stable [Fe(TPP)(NH20H)2]" complex is formed, while at room temperature ( 1/2 of -1.22 V vs. Ag/AgN03 methylene chloride) hydroxylamine reacts with ferric and ferrous Fe(TPP) to form Fe(TPP)NO and ammonia, Eq. (4.44). [Pg.177]

See other pages where Nitrosyl chloride ferric is mentioned: [Pg.95]    [Pg.425]    [Pg.426]    [Pg.614]    [Pg.617]    [Pg.95]    [Pg.1390]    [Pg.158]    [Pg.436]    [Pg.496]    [Pg.950]    [Pg.840]   
See also in sourсe #XX -- [ Pg.617 ]



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Ferric chloride

Nitrosyl chlorid

Nitrosyl chloride

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