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Lewis structures nitromethane

The formula CH3N02 fits more isomers than just nitromethane and methyl nitrite. Some, such as carbamic acid, an intermediate in the commercial preparation of urea for use as a fertilizer, are too unstable to isolate. Given the information that the nitrogen and both oxygens of carbamic acid are bonded to carbon and that one of the carbon-oxygen bonds is a double bond, write a Lewis structure for carbamic acid. [Pg.30]

Similarly, if we treat the nitrogen in nitromethane as a trivalent atom, the index is 1, which is compatible with Figure 1.12. If we treat phosphorus in triphenylphosphine oxide as trivalent, the index is 12, which fits the Lewis structure in Figure 1.12. As an example, let us consider the molecular formula Ci3H9N204BrS. The index of hydrogen deficiency would be 13 - 10/2 + 2/2 + 1 = 10 and a consistent structure would be... [Pg.16]

Figure 1.9 illustrates the construction of a Lewis structure for a more complex example, nitromethane. In this case there are a number of reasonable (according to what we know now) constitutional isomers. Therefore, we must be told the connectivity, or which atoms are bonded to which. Once the connectivity shown in Figure 1.9 is given, the best structure that satisfies the octet rule has some formal charges. This still represents a quite stable molecule. [Pg.14]

As shown in Figure 1.10, two Lewis structures can be written for nitromethane. These structures are different because one has a double bond to one oxygen, whereas the other has a double bond to the other oxygen. Obviously, these structures are equally good representations for nitromethane, because they are of equal stability. [Pg.15]

Two or more correct Lewis structures for the same compound may or may not represent electron distributions of equal energy. Although separate resonance forms do not exist, we can estimate their relative energies as if they did exist. More stable resonance forms are closer representations of the real molecule than less stable ones. The two resonance forms shown earlier for the acetate ion have similar bonding, and they are of identical energy. The same is true for the two resonance forms of nitromethane. The following resonance forms are bonded differently, however. [Pg.1322]

Although the two oxygen atoms in nitromethane appear different in Lewis structures, experiments show that they are equivalent. Both nitrogen-oxygen bonds, for example, are 122 pm in length, midway between the length of a typical N-0 single bond (130 pm) and a typical N=0 double bond (116 pm). In other words, neither of the two Lewis structures for nitromethane is correct by itself the true structure is intermediate between the two. [Pg.44]

The two individual Lewis structures for nitromethane are called resonance forms, and their relationship is indicated by the double-headed arrow between them. The only difference between resonance forms is in the... [Pg.44]

Lewis structures G and H are resonance contributors to the structure of nitromethane. Structural formula I is not a permissible Lewis structure because it has ten electrons around nitrogen. [Pg.22]

Draw the Lewis structure (including resonance structures) for nitromethane (CH3NO2). For each resonance structure, assign formal charges to all atoms that have formal charge. [Pg.405]

Complex 9.12 and its analogues, with other rare earth and alkali metals, have the unique combination of properties of both a Brpnsted base and a Lewis acid. The Li-O bond (Brpnsted base) abstracts a proton from nitromethane. At the same time coordination of the carbonyl oxygen atom to La3+ (Lewis acid) activates the carbonyl group. The formulations for 9.12 and its analogues were first established by a sophisticated mass-spectrometric technique called laser-desorption/ionization time-of-flight (LDI-TOF) mass spectrometry. The molecular structures of several such complexes have subsequently been established by single-crystal X-ray studies. [Pg.225]

Some substances, such as nitromethane, benzene, and acetate ion, can t be represented by a single Lewis or line-bond structure and must be considered as a resonance hybrid of two or more structures, neither of which is correct by itself. The only difference between two resonance forms is in... [Pg.66]

Novel lanthanide fi-diketonate complexes have been synthesized, Their properties include thermal, hydrolytic and oxidative stabilities, volatility, Lewis acidity, and unusually high solubility in nonpolar organic solvents. Various combinations of these properties make lanthanide complexes useful as NMR shift reagents and fuel antiknock additives and in other applications. NMR spectral studies revealed that the Pr(III), Yb(III), and Eu(III) complexes of 1,1,1,2,2,3,3,7,7,7- decafluoro-4,6-heptanedione have sufficient Lewis acidity to induce appreciable shifts in the proton resonances of weak Lewis bases such as anisole, acetonitrile, nitromethane, and p-nitrotoluene. Data from single-crystal structure determinations indicate that the NMR shift reagent-substrate complexes are not stereochemically rigid and that effective axial symmetry may exist by virtue of rapid intramolecular rearrangements. [Pg.222]

In contrast to catalysts 37-39, which are neutral species with dual hydrogen bond donor capability, catalysts such as 40-43 are ionic displaying a hydrogen bond donor site that better resemble the proton (H" ), which is probably the most common Lewis acid found in Nature. The pioneering work carried out by Johnston showed the effectiveness of the chiral proton-based structure 40 in the addition of nitromethane and nitroethane to aryl N-Boc imines (Scheme 29.22) [48]. As a... [Pg.859]


See other pages where Lewis structures nitromethane is mentioned: [Pg.26]    [Pg.26]    [Pg.26]    [Pg.26]    [Pg.33]    [Pg.33]    [Pg.1322]    [Pg.278]    [Pg.64]    [Pg.44]    [Pg.64]    [Pg.64]    [Pg.24]    [Pg.24]    [Pg.44]    [Pg.24]    [Pg.24]    [Pg.14]    [Pg.22]    [Pg.23]    [Pg.45]    [Pg.348]    [Pg.207]    [Pg.314]    [Pg.44]    [Pg.6]    [Pg.403]    [Pg.98]    [Pg.477]   
See also in sourсe #XX -- [ Pg.15 ]




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