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Nitrogen monoxide reversible bonding

In our group we decided to investigate the above mentioned reaction with the stable and monomeric permethylsilicocene. We used LXe and LN2 as totally transparent solvents for IR spectroscopy and were therefore able to characterize the reversible adduct formation with carbon monoxide and nitrogen [4]. The coordinated nitrogen absorbs at 2053 cm", which is value observed in common d-metal nitrogen complexes. For the silicon carbonyl (2065 cm" ) again a back bonded CO is observed, but it is weaker than in Me2SiCO. [Pg.71]

See other pages where Nitrogen monoxide reversible bonding is mentioned: [Pg.218]    [Pg.190]    [Pg.3]    [Pg.317]    [Pg.131]    [Pg.566]    [Pg.190]    [Pg.276]    [Pg.161]    [Pg.162]    [Pg.221]    [Pg.646]    [Pg.166]    [Pg.450]    [Pg.308]    [Pg.5439]    [Pg.231]    [Pg.232]    [Pg.198]    [Pg.188]    [Pg.273]    [Pg.93]   
See also in sourсe #XX -- [ Pg.2 , Pg.2 , Pg.6 , Pg.412 , Pg.771 ]



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