P-Anisidine, 2-nitro

N, JV-Dimethyl-2-nitro-p -toluidine N, JV-Dimethyl-2-nitro-p -anisidine A,jV-E>iethyl-3-nitroaniline A -Dimethyl-d-nitrosoaniline A -Dimethyl-d-nitroaniline A,A-I)iethyl-4-nitroaniline N, A-Diethyl-3-methyl-4-nitro aniline N,N, 3,5-Tetramethyl-4-nitroaniline 4-N,N -Dimethylaminobenzophenone Ethyl 4-Ar,iV-dimethylaminobenzoate 4-(Ar,Ar-Dimethylamino)-/S-nitrostyrene 4-(jV,jV-Dimethylamino)benzaldehyde... 

The 13 scale has been amended and expanded through three subsequent studies. In the first of these (76), the solvatochromic comparison method was applied to three HBD indicators, 2-nitroaniline (6), 2-nitro-p-toluidine (7), and 2-nitro-p-anisidine (8), and their corresponding N,N-dimethyl derivatives (6a, 7a, 8a). 

Dinitroozoonisole or 4,4 -AzobiS (3-nitroonisolo), CH,-0-C H,(N02)>N N-(N0,)C H, 0 CH mw 332.27, N 16.86% bright orn prisms (from nitiobenzene), mp 259°. It was prepd by diazotizing 3-nitro p-anisidine, 0,N(CH,0)C4H,NHi, and treating the diazonium soln with aq CuOH. This action yielded 2,2 —dinitro p,p -bisanisole and a considerable amt of the azobisnitro-anisole obtained from the acetic acid insol resid ie. See also Ref 2 for prepn by oxidation of 4-methoxy2>nitroaniline Refs DW.CLothrop, JACS 64, 1700(1942)... 

Nitro-5-glyceryl methylaniline 3-Nitro-p-hydroxyethylaminophenol 2-Nitro-N-hydroxyethyl-p-anisidine 2-Nitro-p-phenylenediamine 4-Nitro-m-phenylenediamine... 

The reaction of aromatic amines with tetrazine (151) gave either 1,2,4-triazoles (154) or pyrazolo[4,3-e]-l,2,4-triazines (155), depending on the substituents. While aniline, p-toluidine, p-anisidine and p-chloroaniline afford 155, the bromo and p-nitro derivatives give 154. Intermediates 152 and 153 were postulated (Scheme 22) (82CB683). 

TNT forms charge-transfer, or 7r, complexes with polycyclic aromatic hydrocarbons, aromatic amines, and aromatic nitro compds a number of these are listed below in Table 2. The complexes with three amines (diphenylamine, diethyl-aniline, p-anisidine) have characteristic colors this forms the basis for a rapid and convenient thin-layer chromatographic analytical procedure (Ref 34) for the identification of very small amounts of TNT. (For a discussion of the many color reactions of TNT, and of composite expls containing it, see Vol 3, C405-L ff)... 

The following compounds are reported to have been deaminated by decomposing their stabilized diazonijim salts aniline 8 o-, m-, and p-toluidine 6 o-, m-, and p-anisidine 6 o-, m-, and p-nitroaniline 8 2-methoxy-4-nitro-5-aminotoluene 101 m-phenylenediamine 8 wi-tolyl-enediamine 8 p-aminophenol 8 benzidine 8 a- and /3-naphthylamine. . ) ... 

Reference 81 also reports the solid phase enthalpies of formation of the isomeric 4- and 5-nitro-2-methoxyanilines, —197 and —232 kJmol-1. These values are disconcertingly disparate. The two isomers should have very nearly identical enthalpies of formation because in both cases there are electron-donating groups para to the nitro group and so there should be comparable stabilization. From equation 18, an estimated value of solid anisole, and the average enthalpy of formation of m- and p-nitroaniline, a calculated enthalpy of formation of the nitro-o-anisidines is ca — 210 kJ mol-1. 

Cl 37100. See 2-Methyl-4-nitroaniline Cl 37105. See 2-Methyl-5-nitroaniline Cl 37107. See p-Toluidine Cl 37110. See 3-Nitro-p-toluidine Cl 37115. See o-Anisidine hydrochloride Cl 37130. See 2-Methoxy-5-nitroaniline Cl 37225. See Benzidine Cl 37230. See o-Tolidine Cl 37235. See Dianisidine Cl 37240. See N-Phenyl-p-phenylenediamine Cl 37500. See P-Naphthol Cl 40000. See Direct yellow 11 Cl 40002 Cl 40003. See 4,4 -Diaminostilbene-2,2 -disulfonic acid Cl 40645. See Sodium-2-(4-styrvl-3-sulfophenyl)-2H-naphtho-(1,2-d)-triazole Cl 40800... 

Ethanol, 2(2-(2-methoxyethoxy)ethoxy)>. See Triglycol monomethyl ether Ethanol, 2-[(2-methoxy-4-nitrophenyl) amino]-. See 2-Hydroxyethylamino-5-nitroanisole Ethanol, 2-[(4-methoxy-2-nitrophenyl) amino]-. See 2-Nitro-N-hydroxyethyl-p-anisidine Ethanol, 2-methoxy-, stearate. See Methoxyethyl stearate Ethanol, 2-(methylamino)-. SeeN-Methylethanolamine... 

Imexine FD. See N,N -Dimethyl-N-hydroxyethyl-3-nitro-p-phenylenediamine Imexine FE. See 2-Nitro-N-hydroxyethyl-p-anisidine... 

N-(Methoxy (methylthio) phosphinoyl) acetamide. SeeAcephate 2-Methoxynaphthalene P-Methoxynaphthalene. See P-Naphthyl methyl ether 2-Methoxy-5-nitroaniline CAS 99-59-2 EINECS/ELINCS 202-770-5 Synonyms 2-Amino-1-methoxy-4-nitrobenzene 3-Amino-4-methoxynitrobenzene 2-Amino-4-nitroanisole Aniline, 2-methoxy-5-nitro- o-Anisidine nitrate... 

Nitro-N-hydroxyethyl-p-anisidine 57533-90-1 Diisocetyl adipate Schercemol DICA... 

Also prepared from 2-nitro-5-hydroxybenzaldehyde (five steps) or from p-anisidine (one step) [6907,6908]. 

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