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4-Nitro-m-xylene

Titanium ions can also he used as redox catalysts for the indirect cathodic reduction of nitro compounds (417). The electroreduction is carried out in an H20-H2S04/Ti(S04)2-(Pb/Cu) system at 45 80°C under 5 20Am . Nitrobenzene, dinitrobenzene, nitrotoluene, 2,4-dinitrotoluene, 2-nitro-m-xylene, nitro-phenol, 2,4-dinitrophenol, nitrophenetole, o-nitroanisole, 4-nitrochlorotoluene, ni-trobenzenesulfonic acid, and 4,4 -dinitro-stilbene-2,2 -disulfonic acid can all be reduced by this procedure to the corresponding amino compounds (418) in good yields (Scheme 146) [513-516]. Tin... [Pg.577]

M. Warman, Preparation of Trinitro-Meta-Xylene (TNX) , PATM 1728 (1966) [Reported is a procedure for the pilot plant prepn of TNX from m-xylene. The nitration of m-xylene is carried out in two stages 1) The conversion of m-xylene to 2-nitro-m-xylene using mixed add (sulfuric 59/nitric 25/w 16%) at 35 to 50°, and 2) The trinitration of 2-nitro-m-xylene to trinitro-m-xylene, again using mixed add (sulfuric 79/nitric 17.5/w 3.5%), at 95 to 102°. The author states that the overall yield of TNX from m-xylene is as high as 94%. One crystn of the crude product from acet is sufficient to raise the mp to the 182-83° value reported in the literature]... [Pg.415]

Bromo-5-nitrotoluene, AJ38 5-Bromo-2-nitro-m-xylene, AM S... [Pg.622]

Nitro-o-xylene, AN11 l+-Nitro-o-xylene, ANl -2-Nitro-m-xylene, AN13... [Pg.639]

Nitro-o-xylene, 20.3% 2-Nitro-m-xylene, 17.8% 4-Nitro-m-xylene, 82.2%... [Pg.23]

Nitro-m-xylene 2-Nitro-p-xylene 2-Nitro-p-cymene (4) Nitromesitylene... [Pg.530]

Nitro-2,4-diamino-l, 3-dimetbylbenzene, or-yel nds (from w), mp 151-52° readily sol in ale diffc sol in w was prepd by reduction of 4,6-dinitro-2-amino-m-xylene with Aram hydrosulfide (Ref 1) ... [Pg.30]

The 2- isomer predominates in the nitration product, while the 2,5- isomer formed in the nitration of 5-nitro-m-xylene is obtained only in small quantity. [Pg.398]

Nitro Derivatives of Diazoxylenesulfonic Acid 2-Nitro-6-diazo-m xylene-4-sulfonic Acid,... [Pg.76]

See other pages where 4-Nitro-m-xylene is mentioned: [Pg.530]    [Pg.530]    [Pg.634]    [Pg.1386]    [Pg.1386]    [Pg.471]    [Pg.530]    [Pg.333]    [Pg.522]    [Pg.120]    [Pg.220]    [Pg.235]    [Pg.530]    [Pg.530]    [Pg.634]    [Pg.1386]    [Pg.1386]    [Pg.471]    [Pg.530]    [Pg.333]    [Pg.522]    [Pg.120]    [Pg.220]    [Pg.235]    [Pg.116]    [Pg.1158]    [Pg.530]    [Pg.171]    [Pg.175]    [Pg.1386]    [Pg.1386]    [Pg.300]    [Pg.113]    [Pg.105]    [Pg.76]    [Pg.690]    [Pg.724]    [Pg.530]    [Pg.119]    [Pg.120]    [Pg.208]    [Pg.208]    [Pg.76]    [Pg.232]    [Pg.32]    [Pg.212]    [Pg.662]    [Pg.143]   
See also in sourсe #XX -- [ Pg.297 ]



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