Nitro-cyclo-hexane

Ad-nitro-Verbindungen konnen durch Alkohole zu Oximen reduziert werden, wobei es zweckmaBig ist, die Reduktion bei einem pH-Wert von 3 durchzufiihren und als Re-duktionsmedium Wasser oder organische Losungsmittel einzusetzen (s.Bd. X/4, S. 138). Das Verfahren wird speziell zur Herstellung von Cydohexanon-oxim aus Nitro-cyclo-hexan verwendet (s.Bd. X/4, S. 146). 

Nitro-cyclo-hexane cydo-CfTln 02 88.6 370.7 AOP 1994BOR/SAT... 

Nitro-cyclo-hexane cydo-C6Hii-N02 64.0 + 1.5 267.8 + 6.3 Derived from AfH° in ref. 1997VER... 

The final product of the action of nitric acid on hexamine or hexamine dinitrate is RDX see Vol 3, p C614. At low temps, however a number of other compounds are produced (Ref 2). Dilution of the hexamine dinitrate-nitric acid reaction mixture at low temperatures with ethyl ether and subsequent treatment of the gum so obtained with methyl and ethyl alcohols and water severally leads to l-alkoxy-3 5-dinitro-l 3 5-triazacyclohexane (IV), l 3-di-nitro-l 3 5-triaza-n-pentane 5-nitrate (V), and methylenedi-1 -(3 5-dinitro-1 3 5-triaza-cyclo-hexane) (VI). Dilution of the reaction mixture with methyl and ethyl alcohol produces mainly 3 5-dinitro-1 3 5-triazacyclohexane nitrate (II). 

Liquid Hexane Cyclo- hexane Benzene Chloro- benzen Dichloro-ethane Nitro- benze... 

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