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Technetium complexes nitrido

Some recent interest in the technetium chemistry has been focused on complexes possessing a Tc=N3+ core. Tetrachloronitridotechnetate(VI) complexes can easily be synthesized by the reaction of pertechnetate with sodium azide in concentrated hydrochloric acid [34], Although its square-pyramidal structure resembles that of tetrachlorooxotechnetate(V) complexes, stable character of the nitrido complexes in aqueous solution shows a remarkable contrast to the oxo complexes. However, when a strong acid and a coordinating ligand are absent, the interconversion of di(p-oxo)nitridotechnetium(VI) complexes to the monomeric form occurs in the following complicated manner [35]... [Pg.267]

Baidas J (1996) The Chemistry of Technetium Nitrido Complexes. 176 37- 76 Balzani V, Barigelletti F, De Cola L (1990) Metal Complexes as Light Absorption and Light Emission Sensitizers. 158 31-71... [Pg.313]

See other pages where Technetium complexes nitrido is mentioned: [Pg.42]    [Pg.42]    [Pg.42]    [Pg.44]    [Pg.46]    [Pg.48]    [Pg.50]    [Pg.52]    [Pg.54]    [Pg.55]    [Pg.56]    [Pg.56]    [Pg.58]    [Pg.60]    [Pg.62]    [Pg.64]    [Pg.66]    [Pg.68]    [Pg.72]    [Pg.72]    [Pg.73]    [Pg.74]    [Pg.76]    [Pg.78]    [Pg.292]    [Pg.155]    [Pg.99]    [Pg.149]    [Pg.175]    [Pg.183]    [Pg.137]    [Pg.142]    [Pg.225]    [Pg.195]    [Pg.277]   
See also in sourсe #XX -- [ Pg.72 , Pg.73 , Pg.74 , Pg.75 , Pg.76 , Pg.77 , Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.97 , Pg.98 ]

See also in sourсe #XX -- [ Pg.72 , Pg.73 , Pg.74 , Pg.75 , Pg.76 , Pg.77 , Pg.97 , Pg.98 ]



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Nitrido complexes

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Technetium complexes

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