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Nickel hydrogenases thiolate ligands

Kruger, H.-J., Peng, G. and Holm, R. H. (1991) Low-potential nickel(III,II) complexes - new systems based on tetradentate amidate thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [NiFe]-hydrogenases. Inorg. Chem., 30, 734-42. [Pg.268]

The binuclear nickel-thiolate macrocyclic complex (101) displays noteworthy redox behavior, in which one-electron oxidation yields a NP F NP product with significant delocalization of the unpaired electron density onto the bridging thiolate ligands and not onto the second nickel ion. The charge delocalization consequently lies between the two redox extremes of nickel (III)-thiolate and nickel (II)-thiyl radical, thus mimicking the Ni-C state in [NiFe]hydrogenase (see Section 8). [Pg.2883]

See other pages where Nickel hydrogenases thiolate ligands is mentioned: [Pg.184]    [Pg.192]    [Pg.194]    [Pg.31]    [Pg.4332]    [Pg.344]    [Pg.346]    [Pg.440]    [Pg.1585]    [Pg.199]    [Pg.4331]    [Pg.467]    [Pg.238]    [Pg.261]    [Pg.324]    [Pg.207]    [Pg.51]    [Pg.115]    [Pg.121]    [Pg.123]    [Pg.178]    [Pg.192]    [Pg.268]    [Pg.58]    [Pg.500]    [Pg.4195]    [Pg.1573]    [Pg.260]    [Pg.2893]    [Pg.4194]    [Pg.51]    [Pg.296]    [Pg.1674]    [Pg.433]    [Pg.4]    [Pg.239]    [Pg.95]   
See also in sourсe #XX -- [ Pg.54 ]



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Hydrogenase

Hydrogenases nickel

Nickel thiolates

Thiolate

Thiolates

Thiolation

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