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Naturalism, right-wing

Methyl ketone 4 (Scheme 1), the right-wing sector of monensin (1), possesses nineteen of the twenty-six carbon atoms that constitute the backbone of the natural product. Compound 4 is distin-... [Pg.192]

Application of Claisen methodology led to a number of successful total syntheses of natural compounds. Thromboxane B2 has been synthesized from a 4,5-unsaturated sugar derived from D-glucose [126]. The Ireland-Claisen rearrangement [127] is also the key reaction used to control the introduction of the right wing of pseudomonic acids [128]. [Pg.530]

Next, our attention moved to the crucial coupling of the Left-wing 13 and the Right-wing 14. Aldol reactions dealing with 7t-facial selectivity have been extensively studied in natural product synthesis (71). However, reliable prediction of the stereochemical outcome in this coupling cannot be... [Pg.290]

See other pages where Naturalism, right-wing is mentioned: [Pg.207]    [Pg.173]    [Pg.399]    [Pg.24]    [Pg.44]    [Pg.44]    [Pg.46]    [Pg.46]    [Pg.36]    [Pg.270]    [Pg.82]    [Pg.127]    [Pg.1191]    [Pg.158]    [Pg.158]    [Pg.273]    [Pg.88]    [Pg.347]    [Pg.490]    [Pg.127]    [Pg.277]    [Pg.70]    [Pg.4]    [Pg.7]    [Pg.95]    [Pg.87]   
See also in sourсe #XX -- [ Pg.46 ]



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