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Naphthalene diazoquinone sulfonate

Positive photoresists, by contrast, are based on water-soluble novolak resins with naphthalene diazoquinone sulfonate (NDS) as the photosensi-tiser. On photolysis the NDS causes a rearrangement in the polymer to yield nitrogen gas plus an indene carboxylic acid. This latter functional group considerably increases the solubility of the polymer, hence solubilising those areas of the polymer that had been exposed to light. [Pg.129]

The addition of specialized small molecules to a polymer coating is the functional basis for most photoresists. Conventional positive-working photoresists function owing to the difference in solubility caused by the imagewise exposure of a small molecule naphthalene diazoquinone sulfonate ester (NDS). The presence of this small molecule dramatically inhibits the dissolution of the novolac binder while its photodecomposition accelerates the binder dissolution in aqueous base. [Pg.237]

A review of synthetic methods for the most popular photoactive compounds used in diazoquinone resists—DNQ-5-sulfonate and DNQ-4-sulfonate—has been provided by Ershov et al. The synthesis typically begins with naphthalene derivatives, and proceeds via introduction of a sulfonic acid group, followed by diazotization and reaction with thionyl chloride to yield the sulfonic acid chloride (Scheme 7.2). In the next step, the chloride is reacted in a base-catalyzed esterification with a suitable ballast group or backbone, which usually is a multifunctional phenol, less frequently a monofunctional phenol or an aliphatic alcohol. ... [Pg.292]




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Diazoquinone

Diazoquinones

Naphthalene diazoquinone

Naphthalene sulfonates

Naphthalenes sulfonation

Sulfonated naphthalene

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