Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

N-Heterocyclic compounds

Stereocontrolled Additions to Dihydropyridines and Tetrahydropyridines Access to N-Heterocyclic Compounds Related to Natural Products... [Pg.269]

The availability of aniline has made possible a direct study of the reactions of aniline with humic and fulvic acids (Thom et al. 1996), and the detection of resonances attributed to anilinoquinone, imines, and N-heterocyclic compounds are fully consistent with reactions involving quinone and ketone groups. [Pg.287]

N-heterocyclic compounds containing six-membered rings (pyridine and analogues) behave as excellent -acceptors and in turn they provide a rather soft site for metal ion coordination. The 7r-excessive five-membered pyrazole is a poorer 7r-acceptor and a better 7r-donor and it acts as relatively hard donor site. Inclusion of six- and five-membered N-heterocycles like pyridine and pyrazole in one ligand system leads to very attractive coordination chemistry with variations of the electronic properties.555 The insertion of a spacer (e.g., methylene groups) between two heterocycles, which breaks any electronic communication, makes the coordination properties even more manifold. [Pg.294]

Table 14 shows a compilation of the N-heterocyclic compounds present in oil-derived fuels. The boiling point values and their MW have been included to indicate the fraction in which they will most likely be present. [Pg.150]

The cyclizahon of amino alcohols should be an attractive method for the synthesis of N-heterocyclic compounds, mainly because they can be obtained in a single step and without the generation of wasteful byproducts. Carbon-nitrogen bond formation catalyzed by Cp lr complexes has been extended to the synthesis of N-hetero-cyclic compounds by the cyclization of amino alcohols. [Pg.126]

Kita et al. found that phenolic oxidative coupling in case of 272 provides seven-membered N heterocyclic compounds 274 and 275 by bond shift of the initially formed spiro intermediate 273 under suitable conditions. Besides 274 and 275, piperidino-spiroquinone 276 is also formed in this oxidation (Scheme 68). Of particular interest is the recently developed synthesis of amaryllidaceae alkaloids such as (+)-maritidine (Scheme 69) (96JOC5857). [Pg.59]

Sec. III.A] ELECTROLYSIS OF N-HETEROCYCLIC COMPOUNDS 4. Formation of Nitrogen-Nitrogen Bonds... [Pg.277]


See other pages where N-Heterocyclic compounds is mentioned: [Pg.825]    [Pg.566]    [Pg.329]    [Pg.128]    [Pg.323]    [Pg.237]    [Pg.239]    [Pg.241]    [Pg.243]    [Pg.245]    [Pg.251]    [Pg.253]    [Pg.255]    [Pg.259]    [Pg.261]    [Pg.263]    [Pg.265]    [Pg.267]    [Pg.271]    [Pg.273]    [Pg.275]    [Pg.279]    [Pg.281]    [Pg.283]    [Pg.287]    [Pg.293]    [Pg.295]   
See also in sourсe #XX -- [ Pg.102 ]

See also in sourсe #XX -- [ Pg.12 , Pg.445 ]

See also in sourсe #XX -- [ Pg.12 , Pg.445 ]

See also in sourсe #XX -- [ Pg.299 ]

See also in sourсe #XX -- [ Pg.111 ]




SEARCH



N-compounds

© 2024 chempedia.info