N-halogen bonds

The broken bonds (boldface = dissociated atom) BDEs (boldface = recommended data reference in parentheses) kcal/mol kj / mol Methods (reference in parentheses) References 

Note (1) The BDEs in the clusters and complexes of hydrocarbon and carbon ions are listed in Table 24.1  

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S. Berski et al., Dominant role of C-Br - N Halogen bond in molecular self-organization. Crystallographic and quantum-chemical study of Schiff-base-containing triazoles. J. Phys. Chem. B 108, 12327-12332 (2004)... 

Figure 3.1.6 Variation ofX—O/N halogen bond distances (A) with temperature (l<) (error bars +30). Reproduced from Ref. [19] with permission of the American Chemical Society.

Atomic Charges, Bond Lengths, Orders, and Energies of the N-Halogen Bond for Some 1-X-l,2,4-triazoles [98ZOR(ip)J... 

On account of the high reactivity of the N-halogen bond removal of residual halogen from the poly(ether-urethane) after grafting is essential if the material is to be used for biomedical applications. This may readily be effected by reaction with potassium iodide (compare Schuttenbarg and... 

In addition to hydrogen bonds, Metrangolo and coworkers have shown that the [2- -2] photodimerization can be directed in the solid state using a template based on halogen bonds.Cocrystallization of 4,4 -bpe with a halo-genated pentaerythritol (pery) afforded a ID ribbon sustained by I -N halogen bonds (Figure 8). The olefins were... 

An additional absorption band at 2164 cm was interpreted as an overtone 2vs [4]. The position of frequencies and the weaker N-halogen bond were compared to those of the other halogen azides [7]. 

N] halogen bonds by investigation of flexible and structurally restrained [bis (pyridine)halogen] complexes (Fig. 10) [80, 81]. 

Since the submission of this manuscript several publications of importance to its topic have appeared. The [N - Cl - N] and [N - F—N]" halogen bonds of [bis (pyridine)chlorine] and bis(pyridine)fluorine] that were previously only studied... 

Carlsson A-CC, Grafenstein J, Laurila JL et al (2012) Symmetry of [N-X-N]" halogen bonds in solution. Chem Commun 48 1458-1460... 

The degree of electron transfer is correlated to the length of the 1- N halogen bond. In other words, shorter halogen bonds are found with the most ionic compounds, indicated unambiguously an added electrostatic contribution to the halogen bond interaction. 

Gao HY, Zhao XR, Wang H, Pang X, Jin WJ (2013) Cocrystal assembled by 1,2-diiodotetrailuorobenzene and acridine via C-I—N halogen bond and x-hole - F bonds. Chin J Chem 31 1279-1284... 

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