Multiphase polymers impact modified thermoplastic

Multiphase or multicomponent polymers can clearly be more complex structurally than single phase materials, for there is the distribution of the various phases to describe as well as their internal structure. Most polymer blends, block and graft copolymers and interpenetrating networks are multiphase systems. A major commercial set of multiphase polymer systems are the toughened, high impact or impact modified polymers. These are combinations of polymers with dispersed elastomer (rubber) particles in a continuous matrix. Most commonly the matrix is a glassy amorphous thermoplastic, but it can also be crystalline or a thermoset. The impact modified materials may be blends, block or graft copolymers or even all of these at once. 

Multiphase polymers are commonly toughened plastics which contain a soft, elastomeric or rubbery component in a hard glassy matrix or in a thermoplastic matrix. An example of the typical brittle fracture morphology of an unmodified thermoplastic is shown by SEM of nylon (Fig. 5.45A). Addition of an elastomeric phase modifies the brittle fracture behavior of the matrix, as shown in a fracture surface of a modified nylon (Fig. 5.45B). The modification depends on the composition and deformation mechanism of the material [204, 215], but normally it increases the fracture toughness and strength from that of the unmodified matrix resin. Impact strength, as measured for instance by an Izod impact testing apparatus, is affected by the dispersed phase... 

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