MSMPR Product Removal

The crystallizer model that led to the development of equations 44 and 45 is referred to as the mixed-suspension, mixed-product removal (MSMPR) crystallizer. 

Equation (18-31) contains no information about the ciystalhzer s influence on the nucleation rate. If the ciystaUizer is of a mixed-suspension, mixed-product-removal (MSMPR) type, satisfying the criteria for Eq. (18-31), and if the model of Clontz and McCabe is vahd, the contribution to the nucleation rate by the circulating pump can be calculated [Bennett, Fiedelman, and Randolph, Chem. E/ig, Prog., 69(7), 86(1973)] ... 

MSMPR Mixed Suspension, Mixed Product Removal PDF Probability Density Function... 

Growth and nucleation interact in a crystalliser in which both contribute to the final crystal size distribution (CSD) of the product. The importance of the population balance(37) is widely acknowledged. This is most easily appreciated by reference to the simple, idealised case of a mixed-suspension, mixed-product removal (MSMPR) crystalliser operated continuously in the steady state, where no crystals are present in the feed stream, all crystals are of the same shape, no crystals break down by attrition, and crystal growth rate is independent of crystal size. The crystal size distribution for steady state operation in terms of crystal size d and population density // (number of crystals per unit size per unit volume of the system), derived directly from the population balance over the system(37) is ... 

Figure 15.21. Population plots for a continuous mixed-suspension mixed-product removal (MSMPR)...

An MSMPR crystalliser operates with a steady nucleation rate of n = 1013/m4, a growth rate, Gd = 10-8 m/s and a mixed-product removal rate, based on clear liquor of 0.00017 m3/s. The volume of the vessel, again based on clear liquor, is 4 m3, the crystal density is 2660 kg/m3 and the volumetric shape factor is 0.7. Determine ... 

Etherton studied the growth and nucleation kinetics of gypsum crystallization from simulated stack gas liquor using a one-liter seeded mininucleator with a Mixed Suspension Mixed Product Removal (MSMPR) configuration for the fines created by the retained parent seed. The effect of pH and chemical additives on crystallization kinetics of gypsum was measured. This early fundamental study has been the basis for later CSD studies. 

This results In a set of first-order ordinary differential equations for the dynamics of the moments. However, the population balance Is still required In the model to determine the three Integrals and no state space representation can be formed. Only for simple MSMPR (Mixed Suspension Mixed Product Removal) crystallizers with simple crystal growth behaviour, the population balance Is redundant In the model. For MSMPR crystallizers, Q =0 and hp L)=l, thus ... 

However, the mixing of the dispersed and continuous phases is considered here, and it is possible to apply the same way of thinking for plural dispersed phases. Additionally, the newly defined mixedness can be applied to judge whether the assumption of MSMPR (mixed suspension mixed product removal) in the crystallization operation is established. 

ANALYSIS OF DATA FROM A MIXED SUSPENSION—MIXED PRODUCT REMOVAL CRYSTALLIZER (MSMPR) 10.13... 

The first three columns of Table 10.5 show sieve data for a 100-cc slurry sample containing 21.0 g of solids taken from a 20,000-gal (75-m3) mixed suspension-mixed product removal crystallizer (MSMPR) producing cubic ammonium sulfate crystals. Solids density is 1.77 g/cm3, and the density of the clear liquor leaving the crystallizer is 1.18 g/cm3. The hot feed flows to the crystallizer at 374,000 lb/h (47 kg/s). Calculate the residence time r, the crystal size distribution function n, the growth rate G, the nucleation density n°, the nucleation birth rate B°, and the area-weighted average crystal size L3 2 for the product crystals. 

The simplest continuous reactor to consider is that of a constantly stirred tank reactor (CSTR) or precipitator, also called a mixed suspension, mixed product removal crystallizer (MSMPR) [98], shown in Figure 6.23. This tsrpe of precipitator has a constant volume, V, with an input flow rate equal to its output flow rate, Q. The population iJofR) in the precipitator is that which leaves as product. In this case, the population balance is used at steady state (i.e., drjfjdt — 0) ... 

Mixed suspension, mixed product removal crystallizers (MSMPR) normally have much longer operating cycles than... 

If an elutriation leg or other product-classifying device is added to a crystallizer of the MSMPR type, the plot of the population density versus L is changed in the region of largest sizes. Also the incorporation of an elutriation leg destabilizes the crystal-size distribution and under some conditions can lead to cycling. To reduce cycling, fines destruction is usually coupled with classified product removal. The theoretical treatment of both the crystallizer model and the cycling relations is discussed by Randolph, Beer, and Keener (loc. cit.). 

This misconception is particularly common in crystallization. The hypothesis of a perfectly mixed system is, for crystallization and precipitation processes, labeled as mixed-suspension, mixed-product removal (MSMPR). With diis model the crystalUzer is modeled with a spatially homogeneous NDF, generally called the crystal-size distribution (CSD). However, the fact that the CSD is constant through the vessel does not mean that the rates of crystal nucleation, molecular growth, aggregation, and breakage are constant. 

If fouling is a problem, consider flash growth type Pachuca, draft tube MSMPR units, or classified product removal CPR type Oslo, krystall type. 

MSMPR. Mixed-suspension mixed-product removal crystallizer. 

The perfectly mixed, contineous. stendy-state mixed-suspension mixed-product removal (MSMPR) ciys-laHirer is restrictive in the degree to which characteristics of a crystal size distribution can be varied. Indeed, examination of Eqs. (11.2-32) and (11.2-40) shows that once nucleation and growth lunatics are fixed in these systems the crystal size distribution is determined in its entirety. In addition, such distributions have the following characteristics ... 

Once the theoretical yield from a crystallizer has been calculated from mass and energy balances, there remains the problem of estimating the CSD of the product from the kinetics of nucleation and growth. An idealized crystallizer model, called the mixed suspension-mixed product removal model (MSMPR), has served well as a basis for identifying the kinetic parameters and showing how knowledge of them can be applied to calculate the performance of such a crystallizer, ... 

By the use of a generalized population balance the MSMPR modelf is extended to account for unsteady-state operation, classified product removal, crystals in the feed, crystal fracture, variation in magma volume, and time-dependent growth rate. These variations are not included in the following derivations. 

Kougoulos, E., Jones, A.G., Jennings, K.H. and Wood-Kaczmar, M.W. (2005) Use of focused beam reflectance measurement (FBRM) and process video imaging (PVI) in amodified mixed suspension mixed product removal (MSMPR) cooling crystallizer. J Crystal Growth, 273 (3-4), 529-534. 

Nucleation kinetics are often obtained from continuous experiments employing a mixed suspension, mixed product removal (MSMPR) crystallizer and the concepts of the population balances. This technique is also used to obtain crystal growth kinetics. The details of the population balance and its uses will be discussed in Chapter 4 of this volume. A review of methods to estimate nucleation kinetics from batch and continuous experiments can be found in Tavare (1995). 

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