MorLys

The feature that distinguishes intemrolecular interaction potentials from intramolecular ones is their relative strengtii. Most typical single bonds have a dissociation energy in the 150-500 kJ mol range but the strengdi of the interactions between small molecules, as characterized by the well depth, is in the 1-25 kJ mor range. 

It is also possible to explain, from hydration models, the differences between equally-charged cations, such as the alkali metals = 73,5, = 50,1 land 38.68, all in units of mor cm ). From atomic... 

Figure A3.9.6. Population of the first excited vibrational state (u = 1) versus inverse of surface temperature for NO scattering from an Ag(l 11) surface [28], Curves (a) = 102 kJ moC and (b) E = 9 kJ mor ...

Figure C2.1.5. Reduced osmotic pressure FT / (RTc as a function of the weight concentration c of polystyrene (M = 130 000 g mor ) in cyclohexane at different temperatures. At 7"= 35 °C and ambient pressure, tire solution is at tire 0 conditions. (Figure from 1741, reprinted by pennission of EDP Sciences.)...

Once prepared in S q witli well defined energy E, donor molecules will begin to collide witli batli molecules B at a rate detennined by tire batli-gas pressure. A typical process of tliis type is tire collision between a CgFg molecule witli approximately 5 eV (40 000 cm or 460 kJ mor ) of internal vibrational energy and a CO2 molecule in its ground vibrationless state 00 0 to produce CO2 in tire first asymmetric stretch vibrational level 00 1 [11,12 and 13]. This collision results in tire loss of approximately AE= 2349 cnA of internal energy from tire CgFg,... 

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