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Monitoring methods Isotopic analysis

Thorium. Multiple-collector measurement protocols by TIMS for thorium isotopic analysis typically involve the simultaneous measurement of Th and °Th (for silicate rocks), or Th and °Th, then Th and Th (for low- Th samples), using an axial ion counter and off-axis Faraday collector (Table 1). Various methods are used to correct for the relative gain between the low-level and Faraday detectors and 2a-uncertainties of l-5%o are typically obtained (Palacz et al. 1992 Cohen et al. 1992 McDermott et al. 1993 Rubin 2001). Charge-collection TIMS protocols enable Th, °Th and Th to be monitored simultaneously on a multiple-Faraday array and can achieve measurement uncertainties at the sub-permil level (Esat et al. 1995 Stirling et al. 1995). [Pg.48]

In principle, the three isotope method may be widely applied to new isotope systems such as Mg, Ca, Cr, Fe, Zn, Se, and Mo. Unlike isotopic analysis of purified oxygen, however, isotopic analysis of metals that have been separated from complex matrices commonly involves measurement of several isotopic ratios to monitor potential isobars, evaluate the internal consistency of the data through comparison with mass-dependent fractionation relations (e.g., Eqn. 8 above), or use in double-spike corrections for instrumental mass bias (Chapter 4 Albarede and Beard 2004). For experimental data that reflect partial isotopic exchange, their isotopic compositions will not lie along a mass-dependent fractionation line, but will instead lie along a line at high angle to a mass-dependent relation (Fig. 10), which will limit the use of multiple isotopic ratios for isobar corrections, data quality checks, and double-spike corrections. [Pg.17]

See a/so Clinical Analysis Sample Handling. Gas Chromatography Mass Spectrometry. Liquid Chromatography Liquid Chromatography-Mass Spectrometry. Mass Spectrometry Ionization Methods Ovenriew Atmospheric Pressure Ionization Techniques Time-of-Flight Selected Ion Monitoring Stable Isotope Ratio. Peptides. Proteins Traditional Methods of quence Determination. Quality Assurance Internal Standards. [Pg.2916]

Recently, several new methods have been developed for measuring isotope ratios in elemental spedes of some real-world samples, standards, and reference materials using chromatographic separation coupled on-line to MC-ICP-MS. So far, there are about 15 published papers which describe the application of on-line chromatography coupled with MC-ICP-MS to isotopic analysis in elemental species of Hg, Pb, S, Sb, Cl, and Br. In this section, these applications, induding sample preparation, analytical charaderistics of the technique, instrumentation, spedes and isotopes monitored, and some useful results, are discussed. [Pg.509]

The next development has been to do site specific stable isotope analysis (SNIF-NMR). While total or D can now be done by combined GC-MS analysis, which makes the method both sensitive and rapid, site specific analysis requires the isolation and purification of components and nmr time [28]. This adds complexity to the procedure, and it must be recognized that the analysis potentially will alter the isotope distribution/composition of the component being monitored [29]. However, Remaud et al. [28] have demonstrated how this analysis can be applied to the detection of adultered vanilla. [Pg.462]

Huege et al. [271] cultivated Arabidopsis plants in 13C02 atmosphere, transferred the plants to normal atmosphere, and monitored the dilution of isotopes in several metabolite pools. Through evaluation of the mass isotopomer distribution, metabolite partitioning processes could be monitored. However, due to the lack of absolute metabolite concentrations, no absolute fluxes could be calculated. Nevertheless, building upon this method, suitable approaches for flux analysis in autotrophic tissue might be derived in the future. [Pg.164]

Quenched Mixed solutions quenched after a predetermined time controlled by the distance between the mixer and quencher and the flow rate. Tedious but leisurely analysis. Essential for the batch method used in rapid isotopic exchange and low temperature epr monitoring. A 10-20 ms resolution. Large volumes of reactants used ( 5 ml). Commercially available. [Pg.137]


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See also in sourсe #XX -- [ Pg.38 , Pg.176 , Pg.222 , Pg.223 ]




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