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Molecular systems charge transfer affinities

The interaction of nondegenerate molecular or charge-transfer states is insufficient to describe the stability of photoassociation products of molecules with different electronic energy levels, ionization potentials, and electron affinities. On the other hand, treatments26-26 of the exciplex as a pure charge-transfer state afford a quantitative description of the shift in fluorescence peak with solvent polarity and with electron affinity of the (fluorescent) donor in the same quencher-solvent system (Eq. 13) moreover, estimated values for the dipole moment of the emitting species (Table VI) confirm its pronounced charge-transfer character. [Pg.200]

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See also in sourсe #XX -- [ Pg.120 , Pg.168 , Pg.169 , Pg.170 , Pg.171 , Pg.172 ]



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Charge transfer affinities

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