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Molecular magnets oxalate-bridged

Within the area of molecular magnets, oxalate-bridged 3D networks of the type X" "[M M C204)3] are important, and of significance is the introduction of chiral cations X" ". Examples have included enantiomers of [Ru(bpy)2L]+ where HL = 2-phenylpyridine or 8-hydroxyquinoline, which are able to act as chiral templates in the construction of 3D polymeric networks. ... [Pg.620]

Design of molecular magnets based on mechanism (i) has been pursued by Kahn et al The strategy is to employ bridging groups such as the various oxalate derivatives to form extended chains wherein metal centres of different spins (e.g. Cu(II) and Mn(II) alternate. [Cu Mn (pbaOH)]-3H20 is a typical example of this kind. Interestingly, dehydration of a water molecule from this compound raises the to 30 K (Nakatani et... [Pg.455]

See other pages where Molecular magnets oxalate-bridged is mentioned: [Pg.262]    [Pg.427]    [Pg.226]    [Pg.52]    [Pg.222]    [Pg.225]    [Pg.491]    [Pg.1966]    [Pg.13]    [Pg.145]    [Pg.1965]   
See also in sourсe #XX -- [ Pg.303 , Pg.304 , Pg.305 , Pg.306 , Pg.307 , Pg.308 , Pg.309 , Pg.310 , Pg.311 , Pg.312 , Pg.313 , Pg.314 , Pg.315 , Pg.316 , Pg.317 , Pg.318 ]



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