Mohr titration

Either the Mohr titration or the adsorption indicator method may be used for the determination of chlorides in neutral solution by titration with standard 0.1M silver nitrate. If the solution is acid, neutralisation may be effected with chloride-free calcium carbonate, sodium tetraborate, or sodium hydrogencarbonate. Mineral acid may also be removed by neutralising most ofthe acid with ammonia solution and then adding an excess of ammonium acetate. Titration of the neutral solution, prepared with calcium carbonate, by the adsorption indicator method is rendered easier by the addition of 5 mL of 2 per cent dextrin solution this offsets the coagulating effect of the calcium ion. If the solution is basic, it may be neutralised with chloride-free nitric acid, using phenolphthalein as indicator. 

Similar remarks apply to the determination of bromides the Mohr titration can be used, and the most suitable adsorption indicator is eosin which can be used in dilute solutions and even in the presence of 0.1 M nitric acid, but in general, acetic (ethanoic) acid solutions are preferred. Fluorescein may be used but is subject to the same limitations as experienced with chlorides [Section 10.77(b)], With eosin indicator, the silver bromide flocculates approximately 1 per cent before the equivalence point and the local development of a red colour becomes more and more pronounced with the addition of silver nitrate solution at the end point the precipitate assumes a magenta colour. 

Mohr titration analychem Titration with silver nitrate to determine the concentration of chlorides in a solution silver chromate precipitation is the end-point indicator. mor tT tra-shon ... 

Mohr titration Argentometric titration conducted in the presence of chromate. The end point is signaled by the formation of red Ag2Cr04(.v). molality A measure of concentration equal to the number of moles of solute per kilogram of solvent. 

Mohr titration, which involves the formation of a coloured precipitate by reaction with the indicator. For example, in the determination of chloride concentration with silver nitrate a small amount of potassium chromate solution is added as an indicator. This results in the formation of a red silver chromate (Ag2Cr04) precipitate at the end-point ... 

The Mohr titration must be carried out at a pH of 7 to 10 because chromate ion is the conjugate base of the weak chromic acid. Consequently, in more acidic solutions, the chromate ion concentration is too low to produce the precipitate near the equivalence point. Normally, a suitable pH is achieved by saturating the analyte solution with sodium hydrogen carbonate. 

Sulfate and chloride Ion were measured by ion chromatography using a Dionex model 20101 system on samples from Great Sippewissett Marsh. On samples from Great Marsh, sulfate ion was determined gravlmetrically as BaSOj and chloride ion was determined by an argentometric Mohr titration. 

The Mohr titration is performed in slightly alkaline solution. 

In a Mohr titration of chloride with silver nitrate, an error is made in the preparation of the indicator. Instead of 0.011 M chromate indicator in the titration flask at the end point, there is only 0.0011 M. If the flask contains 100 mL at the end point, what is the error in the titration in milliliters of 0.100 M titrant Neglect errors due to the color of the solution. 

USE Catalyst for formation of aldol from alcohol formed at end point of Mohr titration of halides. 

In the Mohr titration, the appearance of a red precipitate, Ag2Cr04, is used to indicate the endpoint. If Kjp(Ag2Cr04) = 10 , what is the [Cr04 ] that will eliminate endpoint error ... 

The precipitable halide halogens in a 15-ml volume of seawater sample are determined by titration with a silver nitrate solution using a chromate end point, the Mohr titration. The silver nitrate solution is standardized against 15 ml of a seawater standard of known chlorinity ( Eau de Mer Normale ), obtainable from the Depot d Eau Normale, Laboratoire Hydrographique, Charlottenlund Slot, Copenhagen, Denmark. Corrections are made to allow for temperature and density, so as to convert titration values to chlorinity, from which salinity values are obtained. Special Knudsen-type automatic pipettes and burettes are used. 

The precipitable halide halogens in a 10-ml volume of sea water are determined by titration with a silver nitrate solution using a chromate end point, the Mohr titration. The silver solution is standardized against 10 ml of sea water of known chlorosity. 

In the Mohr titration, Cl (aq) is titrated with AgN03(aq) in solutions that are at about pH = 7. Thus, it is suitable for determining the chloride ion content of drinking water. The indicator used in the titration is K2Cr04(aq). A red-brown precipitate of Ag2Cr04(s) forms after all the Cl has precipitated. The titration... 

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