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Modeling level process

Effective with the 1982 model year, particulate matter from diesel vehicles was regulated by the U.S. Environmental Protection Agency for the first time, at a level of 0.37 gm km . Diesel vehicles were allowed to meet an NO level of 0.93 gm km under an Environmental Protection Agency waiver. These standards were met by a combination of control systems, primarily exhaust gas recirculation and improvements in the combustion process. For the 1985 model year, the standards decreased to 0.12 gm of particulate matter per kilometer and 0.62 gm of NO per kilometer. This required the use of much more extensive control systems (1). The Clean Air Act Amendments of 1990 (2) have kept the emission standards at the 1985 model level with one exception diesel-fueled heavy trucks shall be required to meet an NO standard of 4.0 gm per brake horsepower hour. [Pg.526]

The meteoric rise in computer power (and meteoritic decline in hardware prices) has opened exciting avenues for computer modeling in all branches of science. Today, computer models are used in three main areas of catalysis research modeling of reaction pathways and catalytic cycles, modeling of process kinetics and reaction performance, and computing structure/activity relationships on various levels. The models cover a wide range of approaches and system types. [Pg.28]

The bed scale corresponds to the whole bed or to a volume containing a large number of particles. That is the level at which we want to derive models for the investigated transport processes. However these processes are generally ruled by gas-liquid-solid interactions occurring at the particle scale. That is the reason why it is necessary to model these processes at the particle scale. The change of scale or volume averaging between both levels is ruled by the percolation process, i.e., by the velocity distribu-... [Pg.411]

This second-level modeling of the feedback mechanisms leads to nonlinear models for processes, which, under some experimental conditions, may exhibit chaotic behavior. The previous equation is termed bilinear because of the presence of the b [y (/,)] r (I,) term and it is the general formalism for models in biology, ecology, industrial applications, and socioeconomic processes [601]. Bilinear mathematical models are useful to real-world dynamic behavior because of their variable structure. It has been shown that processes described by bilinear models are generally more controllable and offer better performance in control than linear systems. We emphasize that the unstable inherent character of chaotic systems fits exactly within the complete controllability principle discussed for bilinear mathematical models [601] additive control may be used to steer the system to new equilibrium points, and multiplicative control, either to stabilize a chaotic behavior or to enlarge the attainable space. Then, bilinear systems are of extreme importance in the design and use of optimal control for chaotic behaviors. We can now understand the butterfly effect, i.e., the extreme sensitivity of chaotic systems to tiny perturbations described in Chapter 3. [Pg.361]

In our previous papers , we have shown that collective jump motions of atoms take place in highly supercooled fluid states, mainly contributing to the a relaxation, and therefore represents the molecular-level mechanisms. The main purpose of this paper is to study both a and / relaxations from S q,u>) and x (9,w) in a supercooled fluid by a super-long-time molecular dynamics (MD) simulation for a model fluid of binary soft-sphere mixtures. In particular, we focus on studying the type of each relaxation (Debye or non-Debye ) and the molecular-level processes for the / relaxation. [Pg.123]

Several requirements have been put forward in order to model chemisorption processes in infinite surfaces with metal clusters. The ground state wave function should have a conduction band near the Fermi level with significant amplitude near the chemisorption site. The cluster should exhibit a high density of states and should be highly polarizable. It should also possess an ionization potential similar to that of the bulk. Finally, the orbital structure of the cluster employed in the model must be in a suitable bonding state, which is often not the ground state. However, this rule implies that it is not important to describe the density of states, the ionization potential, or, the polarizability of the bulk with the cluster system in order to obtain stable chemisorption energies. [Pg.204]


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