Mobile order and disorder

In the framework of the mobile order and disorder (MOD) theory five components contribute most to the Gibbs free energy of partitioning of a solute in a biphasic system of two essentially immiscible solvents [23] ... 

Ruelle, P. Universal model based on the mobile order and disorder theory for predicting lipophilidty and partition coefficients in all mutually immiscible two-phase liquid systems. Chem. Inf. Comput. Sci. 2000, 40, 681-700. 

Ruelle P. The n-octanol and n-hexane/water partition coefficient of environmentally relevant chemicals predicted from the mobile order and disorder (MOD) thermodynamics. Chemosphere 2000 40 457-512. 

Chickos, J.S., Nichols, G. and Ruelle, P. (2002) The estimation of melting points and fusion enthalpies using experimental solubilities, estimated total phase change entropies, and mobile order and disorder theory. /. Chem. Irf. Comput. Sci, 42, 368-374. 

Lan Y-K, Huang C-I (2009) Charge mobility and transport behavior in the ordered and disordered states of the regioregular poly(3-hexylthiophene). J Phys Chem B 113 14555-... 

Heat capacity between that of ice and liquid water ACpi - - 0.2 cal K-1 g 1 Normalization of pK at 0.05 gg-1. Knee in adsorption isotherm. Native state very stable At 0.07 gg-1 transition in surface water, from disordered to ordered and/or from dispersed to clustered state seen in IR and EPR spectroscopic and thermodynamic properties associated with completion of charged group hydration Water mobility ca. 100 x less than for bulk water increased motion with increased hydration. Bound ligand mobility r constant from 0-0.2gg-1 t = 4x10-9s. Enzymatic activity negligible. 

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