Mineral angles

Clearly, it is important that there be a large contact angle at the solid particle-solution-air interface. Some minerals, such as graphite and sulfur, are naturally hydrophobic, but even with these it has been advantageous to add materials to the system that will adsorb to give a hydrophobic film on the solid surface. (Effects can be complicated—sulfur notability oscillates with the number of preadsoibed monolayers of hydrocarbons such as n-heptane [76].) The use of surface modifiers or collectors is, of course, essential in the case of naturally hydrophilic minerals such as silica. 

Table 1 Hsts some of the physical properties of duoroboric acid. It is a strong acid in water, equal to most mineral acids in strength and has a p p o of —4.9 as compared to —4.3 for nitric acid (9). The duoroborate ion contains a neady tetrahedral boron atom with almost equidistant B—F bonds in the sohd state. Although lattice effects and hydrogen bonding distort the ion, the average B—F distance is 0.138 nm the F—B—F angles are neady the theoretical 109° (10,11). Raman spectra on molten, ie, Hquid NaBF agree with the symmetrical tetrahedral stmcture (12).

Interior acute angle between optic axes of biaxial mineral. 

The sharpness of separation of the mineral from the gangue is dependent on (1) the stability of the suspension, which is influenced by the size of the medium (2) the specific gravity of the medium (3) the cleanliness of the medium (4) the cone angle (5) the size and ratios of the internal openings in the cyclone (inlet, apex, and vortex) and (6) the pressure at which the pulp is introduced into the cyclone. A 20° cone angle is the most common. Cyclone diameter will be determined by the separation to be made as well as by the capacity required. The 0.5- and 0.6-m (20- and 24-in) cyclones are most common in coal plants, whereas multiple cones of 0.25- or 0.3-m (10- or 12-in) diameter are used in higher-gravity separations. 

Disilicates, containing the discrete Si207 ) unit, are rare. One example is the mineral thortveitite, Sc2Si207, which features octahedral Sc " (r 75 pm) and a linear Si O Si bond between staggered tetrahedra (Fig. 9.4a). There is also a series of lanthanoid disilicates I.n2Si207 in which the Si-O-Si angle decreases progre.ssively... 

J. w. Geus, The interlayer collapse during dehydration of synthetic Na -beidellite a %a solid -state magic-angle spinning NMR study. Clays Clay Minerals. 25 457 (1992). 

B) Contact between air, water and mineral where the mineral phase has a plane surface. 0 is the contact angle and the water wets the mineral. 

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