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Micellar aggregation numbers temperature effect

In aqueous solution micelles are generally thought to be spherical as long as the surfactant concentration remains close to the critical micelle concentration. Rod-like micelles may form at higher surfactant concentrations [1, 2]. Addition of a third component such as neutral salt or non-electrolytes may favour longer micellar structures, for instance rod-like micelles [3-6]. An increase in temperature, on the other hand, seems to favour spherical micelles [7, 8]. The effect of pressure on the shape transition point is not known, though it appears that the aggregation number of micelles decrease with pressure at least up to about 160 MPa [9-12]. [Pg.34]


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See also in sourсe #XX -- [ Pg.119 , Pg.120 ]




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