Methylamine, oxidation

The antistatic agent, iV-di-[3-(stearoylamino)propyl]-7V-methylamine oxide, (I), was prepared by Baik et al. (3) and used as a fabric softer in fabric detergent compositions. 

The borane is prepared by reaction of B—CH30-9-BBN with CH3Li and then tri-methylamine oxide. 

Raymond, J.A., and A.L. DeVries (1998). Elevated concentrations and synthetic pathways of tri-methylamine oxide and urea in some teleost fishes of McMurdo Sound, Antarctica. Fish. Physiol. Biochem. 18 387-398. 

Van Spanning, R. J. M., Wansell, C. W., Reijnders, W. N. M., Oltmann, L. F., and Stouthamer, A. H., 1990, Mutagenesis of the gene encoding amicyanin of Paracoccus denitrificans and theresultant effect on methylamine oxidation, FEBS Lett. 275 217n220. 

A coordinate-covalent bond, represented by an arrow, is one in which both electrons come from the same atom that is, the bond can be regarded as being formed by the overlap of an orbital containing two electrons with an empty one. Thus tri-methylamine oxide would be represented... 

The dark red, volatile, tris[bis(trimethylsilyl)amido] uranium(III) can be made from a solution of UClaTHFn and the sodium bis(trimeth-ylsilyl)amide. It is monomeric and contains 3-coordinate uranium (285). It has no tendency to act as an acceptor, but it reacts with tri-methylamine oxide or oxygen to yield the uranium(V) compound OU[N(SiMe3)2l3. 

CL-Keioacylsilanes. Reaction of (Z)-vinylsilanes (1), with OSO4 and tri-methylamine oxide gives the cw-l,2-diols (2) in moderate yield. These can be oxidized by DMSO/oxalyl chloride to a-keto acylsilanes (3, 40-55% yield). 

U.S. 4659565 (1987) Smith et al. (Ethyl Corp.) Di Cg-Cis alkyl methylamine oxide... 

Oxamin LO. [ICI Australia] Lauryl di-methylamine oxide detergent, food foamer and foam stabilizer f(x pmonal care prods, and dete ent fwmulations. 

Treatment of [RuCl(NHj)5] with Ag(02CCFj), followed by zinc amalgam reduction and addition of amine yields [Ru(L)(NH3)5] (L = cyclohexylamine, benzylamine, methylamine). Oxidation of these complexes with Btj produces the corresponding ruthenium(III) species [Ru(L)(NH3)5]. Subsequent oxidation of the amine ligand can readily occur to give imine and nitrile products, explaining the relatively few complexes of this type that have been isolated (see Section 45.4.2). 

APC allophyoocyanin Chi chlorophyll HEPES 4-(2-hydroxy-ethyl)-1-piperazineethane sulfonic acid UDAO lauryldi-methylamine oxide MES 4- moirpholine-ethane sulfonic acid PS photosystem SB sulfobetaine SDS sodium dodecyl sulfate... 

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