Methyl o-tolyl ether

Methoxytoluene o-Methoxytoluene 2-Methylanisole 2-Methylmethoxybenzene Methyl o-methyl phenyl ether Methyl o-tolyl ether o-Tolyl methyl ether... 

Methyl o-tolyl ether. See o-Methylanisole Methyl-p-tolyl ether. See p-Methylanisole Methyl p-tolyl ketone. See4 -Methyl acetophenone... 

Di-benzyl ether Methyl o-tolyl ether 0.540 0.129 2-Butoxyethanol 1.21... 

Among the features of Volume 41 is the smallest-scale synthesis yet published in Organic Syntheses, namely, the preparation of 0.0005 mole of cholestanyl methyl ether by a generally useful methylation procedure that employs diazomethane and fluoboric acid (p. 9). Two preparations of isocyanides by dehydration of formamides are included. One of these, illustrated by cyclohexyl isocyanide (p. 13), is most suitable for aliphatic isocyanides while the other, illustrated by o-tolyl isocyanide (p. 101), is most suitable for aromatic isocyanides. 

Tolman has shown that the equilibrium constants for the reactions of 38 substituted alkenes with Ni[P(0-o-tolyl)3]3 (13) in benzene, to form (ENE)bis(tri-o-tolylphosphite)nickel complexes (14), are sensitive to the structure of the alkene (equation 13). Values of K[ at 25 °C vary from 10 to 4 x 10. The stability of the complex is enhanced by electron-withdrawing substituents such as cyano and car-boxy and lowered by alkyl groups. That resonance involving unshared electrons on the oxygen of an al-koxy group overpowers the inductive effect is indicated by the relative values of Ki for allyl methyl ether, 1-hexene and vinyl butyl ether which diminish in that order by factors of 3 1 0.006. 

Methylbenzoic acid methyl ester. See p-Cresyl acetate Methyl p-toluate Methyl benzoin. See Benzoin methyl ether Methylbenzol. See Toluene 2-Methyl benzophenone CAS 131-58-8 EINECS/ELINCS 205-032-0 Synonyms 2-Benzophenone, methyl- (2-Methylphenyl) phenylmethanone Phenyl tolyl ketone Phenyl-o-tolyl-methanone Classification Aromatic ketone Empirical C14H12O... 

The preparation of crystalline methyl ethers of iV-phenyl- or Af-p-tolyl-aldosylamine by condensation of aniline or p-toluidine with aldose methyl ethers proceeds, in many cases, readily and quantitatively in methanolic or ethanolic solution, either at room or reflux temperature. For this reason, such derivatives are frequently used to characterize aldose methyl ethers isolated during constitutional studies on polysaccharides. For D-glucose, for example, crystalline 2-0-methyl-, 6-0-methyl-,3,4-di-O-methyl-, 2,3,4-tri-O-methyl-, 2,4,6-tri-O-methyl-, " and 2,3,4,6-tetra-O-methyl-A-phenyl-n-glucosylamine have been prepared in this way. Although anomeric forms of A -arylaldosylamine methyl ethers are possible, such anomeric pairs have not been isolated. No similar derivatives have been obtained from ketose methyl ethers. 

Mt-Dunetfiylhenzyl Alcohol. at4-Dimethylben-zenemethanol p-tolylmethylcarbinol meihyl-p-tolylcarbi-nol 4 (o-hydroxyethyl)toluene 4-methyl-a-phenethyl alcohol l -p-tolyl-1-ethanol. CjH O m l wt 136.19. C 79.37%, H 8.88%, O 11,75%. Constituent of the essential oil from CurcumQ longa L., Ztngiberaceae and related plants Dieterie, Kaiser. Arch. Pharm. 271, 337 (1933). Prepd from p-tolylmagnesium bromide and acetaldehyde in ether v. 

Ether, 2-chloro-o,a,a-trifluoro-p-tolyl 3-ethoxy-4-nitrophenyl. See Oxyfluorfen Ether cyanatus. See Propionitrile Ether, decyl methyl. See Decyl methyl ether Ether, 2,4-dichlorophenyl p-nitrophenyl. See Nitrofen... 

CAS 55-38-9 EINECS/ELINCS 200-231-9 Synonyms 0,0-Dimethyl-0-4-(methylmercapto)-3-methylphenyl phosphorothioate 0,0-Dimethyl O- [3-methyl-4-(methylthio) phenyl] phosphorothioate 0,0-Dimethyl-0- [4-(methylthio)-m-tolyl]phosphorothioate Mercaptophos 4-Methylmercapto-3-methylphenyl dimethyl thiophosphate Empirical C10H15O3PS2 Formula (CH30)2P(S)0C6H3(CH3)SCH3 Properties Brown liq., si. odor of garlic insol. in water sol. in mostorg. soivs., alcohol, ether, acetone, esp. chlorinated hydrocarbons m.w. 278.34 dens. 1.250 (20/4 C) b.p. 105 C (0.01 mm) ref. index 1.5698 (20 C)... 

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