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Methyl nitril

The compatibility of sodium hydride with electrophiles means that, by adding two equivalents of base, alkylation can be encouraged to occur more than once. This dimethylated acid was required in the synthesis of a potential drug, and it was made in two steps from a nitrile. Double alkylation with two equivalents of NaH in the presence of excess methyl iodide gave the methylated nitrile which was hydrolysed to the acid. The monoalkylated product is not isolated—it goes on directly to be deprotonated and react with a second molecule of Mel. [Pg.665]

Propansaure 2-Dibromamino-2-methyl- -nitril E16a, 934 (NCl2- NBr2)... [Pg.151]

Propansaure 2-Hydroxy-2-methyl- -nitril VIII, 276 (R2CO +... [Pg.160]

Butansanre 2-Hydroxylamino-3-methyl- -nitril X/l, 1121, 1123 Diazen l-Methyl-2-(2-methyl-l-propenyl)- -1-oxid El5/1, 1092 (N-Oxigenier.)... [Pg.225]

Cydopropen 1-Cyan-3,3-dimethyl-E19b, 693/1209 (In + Carben) trans,tran.v-2,4-Hexadiensaure -nitril ES, 1332 (COOH - CN) 23-Pentadiensaure 4-Methyl- -nitril ES, 1462 (Br - CN)... [Pg.272]

S/S-Acetal +1,2-Diamin) Malonaldehvdsaure (Dimethyl-amino-methyl)- -nitril E3, 161 (aus En-amin)... [Pg.295]

Pentansaure 2-Hydroxylamino-4-methyl- -nitril X/l, 1121, 1123 3H-Pyrazol 3-Hydroxy-3,5,5-trimethyl-4,5-dihydro- E14a/2, 467 (O-CO-R OH) Pyrimidin... [Pg.312]

Pentansanre 4-Acetoxy-2-chlor-4-methyl- -nitril E19a, 802 (R-HgX + En)... [Pg.507]

E18, 1032 (Allen + Amin) Butansaure 2-Isopropyl-3-methyl- -nitril E5, 1376... [Pg.535]

See other pages where Methyl nitril is mentioned: [Pg.897]    [Pg.919]    [Pg.422]    [Pg.179]    [Pg.114]    [Pg.351]    [Pg.86]    [Pg.22]    [Pg.152]    [Pg.153]    [Pg.153]    [Pg.160]    [Pg.163]    [Pg.165]    [Pg.165]    [Pg.207]    [Pg.207]    [Pg.211]    [Pg.211]    [Pg.219]    [Pg.219]    [Pg.304]    [Pg.305]    [Pg.380]    [Pg.395]    [Pg.395]    [Pg.411]    [Pg.413]    [Pg.413]    [Pg.502]    [Pg.511]    [Pg.526]    [Pg.535]    [Pg.536]    [Pg.657]   
See also in sourсe #XX -- [ Pg.371 , Pg.553 ]



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3-Methyl-2-butene nitrile

Hydrocarbons, hydrocarbon nitriles (methyl groups

Methyl nitrile

Methyl nitrile

Methyl nitrile, substitution

Methyl- - -ester-nitril

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Nitriles acid methyl esters

Nitriles hydrocarbons (methyl

Nitriles methyl esters

Nitriles, Dithioacetals, and Methyl Ethers

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