Methanethiol hydration

Mercury(II) oxide Chlorine, hydrazine hydrate, hydrogen peroxide, hypophosphorous acid, magnesium, phosphorus, sulfur, butadiene, hydrocarbons, methanethiol... [Pg.1209]

ACETATO MERCURIOSO (Spanish) (21908-53-2) A strong oxidizer. Violent reaction with reducing agents, acetyl nitrate, diboron tetrafluoride, disulfur dichloride, combustible materials, fuels, hydrazine hydrate, hydrogen peroxide, hydrogen trisulfide, hypophospho-rous acid, methanethiol, phospham. sodium-potassium alloy, sulfur, sulfur trioxide. Incompatible with alcohols, alkali metals, ammonium nitrate, diboron tetrafluoride, hydrazinium nitrate, hydrogen sulfide, nitroalkanes, rubidium acetylide, selenium oxychloride. Forms heat-, friction-, or shock-sensitive explosives with anilinium perchlorate, chlorine, phosphorus,. sulfur, magnesium, potassium, sodium-potassium alloy. May increase the explosive or thermal sensitivity of nitromethane, nitroethane, 1-nitropropane and other lower nitroalkanes, silver azide, hydrazinium perchlorate. Slowly decomposes on exposure to air. [Pg.6]

YELLOW OXIDE of MERCURY (21908-53-2) A strong oxidizer. Violent reaction with reducing agents, acetyl nitrate, diboron tetrafluoride, disulfur dichloride, combustible materials, fuels, hydrazine hydrate, hydrogen peroxide, hydrogen trisulfide, hypophosphorous acid, methanethiol, phospham, sodium-potassium alloy, sulfur, sulfur trioxide. Incompatible with... [Pg.1245]

The synthesis of diclomezine starting from l-(3,5-dichloro-4-methylphenyl)-ethanone, according to the literature [56], is shown in Scheme 21.4. It starts with an aldol condensation of the acetophenone with glyoxylic acid, yielding the corresponding benzoylacrylic acid. Addition of sodium methanethiolate in water affords 4-(3,5-dichloro-4-methylphenyl)-2-methylsulfanyl-4-oxo-butyric acid. The latter can be cyclized with hydrazine hydrate in ethanol to afford 6-(3,5-dichloro-4-methylphenyl)-4-methylsulfanyl-4,5-dihydro-(2H)-pyridazin-3-one, which can be aromatized under acidic conditions by elimination of methyl mercaptan to generate diclomezine. [Pg.720]