Methanesulfonate, trifluoro

FjFeOoSQHs, Methanesulfonate, trifluoro-, tricarbonyl(T -cyclopentadienyl)iron-(1-h), 24 161... [Pg.260]

O3F3SC, Methanesulfonate, trifluoro-metal complexes and salts, 24 243-306 O3F11PQH6, Phosphane, difluorotris(2,2,2-trifluoroethoxy)-, trans-, 24 63 03FeP2C,Hi8, Iron, tricarbonyIbis(trime-thylphosphone)-, 25 155 03FeP2C27Hs4, Iron, tricarbonyIbis(tributyI-phosphine)-, 25 155... [Pg.282]

SCSFO4, Cesium fluorine sulfate, 24 22 SFN, Thiazyl fluoride, 24 16 SF2HN, Imidosulfurous difluoride mercury complex, 24 14 SF3Fe06C9H5, Methanesulfonate, trifluoro-, tricarbonyl(it -cyclopentadienyl)iron-(H-), 24 161... [Pg.294]

SF3O3C, Methanesulfonate, trifluoro-metal complexes and salts, 24 243-306 (SN Sulfur nitride, polymer, 22 143 SNC, Thiocyanate... [Pg.294]

This method for the preparation of cyclobutanone via oxaspiropentane is an adaptation of that described by Salaiin and Conia. The previously known large-scale preparations of cyclobutanone consist of the reaction of the hazardous diazomethane with ketene, the oxidative degradation or the ozonization in presence of pjrridine of methylenecyclobutane prepared from pentaerythritol, or the recently reported dithiane method of Corey and Seebach, which has the disadvantage of producing an aqueous solution of the highly water-soluble cyclobutanone. A procedure involving the solvolytic cyclization of 3-butyn-l-yl trifluoro-methanesulfonate is described in Org. Syn., 54, 84 (1974). [Pg.40]

Part C of the present procedure illustrates a mild method for effecting the elimination of thiophenol from thioacetals and thioketals under essentially neutral conditions. The reaction of simple thioacetals and thioketals with bis[copper(I) trifluoro-methanesulfonate] benzene complex in benzene-tetrahydrofuran at room temperature affords vinyl sulfides in high yield (Table I). The reaction presumably occurs by coordination of the thiophilic copper(I) reagent with sulfur, heterolysis to a phenylthio-stabilized... [Pg.105]

As mentioned several times Lewis acids are highly valuable catalysts but the most commonly used ones such as aluminium chloride and boron trifluoride are highly water sensitive and are not usually recovered at the end of a reaction, leading to a significant source of waste. In recent years there has been much research interest in lanthanide triflates (trifluoro-methanesulfonates) as water stable, recyclable Lewis acid catalysts. This unusual water stability opens up the possibility for either carrying out reactions in water or using water to extract and recover the catalyst from the reaction medium. [Pg.113]

EDA = ethyl diazoacetate MDA = methyl diazoacetate OTf = 03SCF3 (trifluoro-methanesulfonate) acac = acetylacetonate hfacac = hexafluoroacetylacetonate. [Pg.78]

Methoxy-4 -nitrobiphenyl 1,1 -Biphenyl, 4-methoxy-4 -nitro- (9) (2143-90-0) 4-Nitrophenyl trifluoromethanesulfonate Methanesulfonic acid, trifluoro-, p-nitrophenyl ester (8) Methanesulfonic add, trifluoro-, 4-nitrophenyl ester (9) (17763-80-3)... [Pg.54]

Nitrophenol Phenol, p-nitro- (8) Phenol, 4-nitro- (9) (100-02-7) Trifluoromethanesulfbnic anhydride Methanesulfonic acid, trifluoro-, anhydride (8,9) (358-23-6)... [Pg.54]

Bromoanlsole Anisole, o-bromo- (8) Benzene, 1-bromo-2-methoxy- (9) (578-57-4) Methyl trifluoromethanesulfonate Methanesulfonic add, trifluoro-, methyl ester (8,9) (333-27-7)... [Pg.195]

In a Schlenk tube equipped with a magnetic stirrer bar were placed (S,S)-1,2-bis(boranato(tert-butyl)methylphosphino)ethane (2) (131 mg) and dry toluene (4mL) under an argon atmosphere at 0°C. To this solution, trifluoro-methanesulfonic acid (0.22 mL) was added over a period of 5 minutes. [Pg.125]

In this paper we report on the use of trifluoro-methanesulfonates (Table 1) of 4-N, N-dimethylamino-benzenediazonium (Dl) and 4-methoxybenzene-diazonium (D2) as CEL dyes, negative working sensitizers, and photoacid generators for chemical amplification resist systems(11). [Pg.320]

ACETALDEHYDE, 53, 104 PREPARATION OF VINYL TRIFLUORO-METHANESULFONATES 3-METHYL-... [Pg.64]

Hexylethenyl triflates Methanesulfonic acid, trifluoro-, 1 -methyleneheptyl ester (11) (98747-02-5)... [Pg.95]

Bicyclo[2.2.1]hepta-2,5-diene-l,4-bis(diphenylphosphino)butanerhodium trifluoromethanesulfonate Rhodiura(l+), [(2,3,5,6- )-bicyclo[2.2.1]hepta-2,5-diene][l, 4-butanediylbi s[diphenyl phosphine]- ,P ]-, tri f1uoromethanesulfonate Bicyclo[2.2.l]hepta-2,5-diene-2,4-pentanedionatorhodiurn Rhodium, (2,5-norbornadiene) (2,4-pentanedionato)- (8) Rhodium, [(2,3,5,6- )-bicyclo[2.2.l]hepta-2,5-diene] (2,4-pentanedionato-0,0 )- (9) (32354-50-0) Trimethylsilyl trifluoromethanesulfonate Methanesulfonic acid, trifluoro-, trimethylsilyl ester (8,9) (27607-77-8)... [Pg.39]

Dibutylboron triflate Methanesulfonic acid, trifluoro-, anhydride with dibutylborinic acid (9) (60669-69-4)... [Pg.174]

Gazeau-Bureau S, Delcroix D, Martin-Vaca B, Bourissou D, Navarro C, Magnet S (2008) Organo-catalyzed ROP of e-caprolactone methanesulfonic acid competes with trifluoro-methanesulfonic acid. Macromolecules 41 3782-3784... [Pg.212]

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