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Methane bond alkenes

The C—H bonds of hydrocarbons show little tendency to ionize and alkanes alkenes and alkynes are all very weak acids The acid dissociation constant for methane for exam pie IS too small to be measured directly but is estimated to be about 10 ° (pK 60)... [Pg.368]

Note that there is no one-carbon alkene corresponding to methane, since hydrogen can never form more than one covalent bond, and there is no other carbon atom in the structural formula. Therefore, the first compound in the alkene series is ethene, while the corresponding two-carbon compound in the alkane series, ethane, is the second compound in the series, with methane the first. [Pg.187]

Carbon forms a huge number of binary compounds with hydrogen. Three major categories of these compounds are alkanes, alkenes, and alkynes. An alkane has only single bonds between carbon atoms. The four simplest alkanes, which are shown in Figure 3-7. are methane, ethane, propane, and butane. An alkene, on the other hand, contains one or more double bonds between carbons, and an alkyne has one or more triple bonds between carbon atoms. Figure shows the structures of ethylene, the simplest alkene, and acetylene, the simplest alkyne. [Pg.136]

Reactions and Properties of Phosphonic and Phosphinic Acids and their Derivatives.-A free radical mechanism has been proposed to account for the cleavage of the phosphorus-carbon bond in the alkylphosphonic acids (155) by E coli to give a mixture of alkane (methane only, from methylphosphonic acid) and terminal alkene. [Pg.167]

The mechanism for the reaction catalyzed by cationic palladium complexes (Scheme 24) differs from that proposed for early transition metal complexes, as well as from that suggested for the reaction shown in Eq. 17. For this catalyst system, the alkene substrate inserts into a Pd - Si bond a rather than a Pd-H bond [63]. Hydrosilylation of methylpalladium complex 100 then provides methane and palladium silyl species 112 (Scheme 24). Complex 112 coordinates to and inserts into the least substituted olefin regioselectively and irreversibly to provide 113 after coordination of the second alkene. Insertion into the second alkene through a boat-like transition state leads to trans cyclopentane 114, and o-bond metathesis (or oxidative addition/reductive elimination) leads to the observed trans stereochemistry of product 101a with regeneration of 112 [69]. [Pg.241]

Merritt et al. [124,170-174] carried out some of the earliest additions of fluorine to carbon-carbon double bonds. The fluorination of cis and trans propenyl benzene in a nonpolar solvent at low temperature gave predominantly erythro and threo difluorides respectively. More recently, Rozen [175] carried out similar reactions, but used a more polar solvent (trichlorofluoro methane, chloroform and ethanol) and a very low concentration of fluorine. Thus, in the fluorination of cis and trans 3-hexene- l-ol acetate (Fig. 72), syn addition occured to give exclusively the erythro and threo difluoro compounds respectively. Corresponding results were obtained in the addition of fluorine to other alkenes, including cyclic alkenes and cyclic enones. [Pg.28]

Under pyrolytic conditions at temperatures above 300°C, generally within 500-800°C, the pyrolysis reaction forms alkenes by carbon-hydrogen bond scissions. An early experiment, where propane was heated to 575°C for 4 min in a silica flask, yielded propylene by dehydrogenation [Eqs. (2.19)-(2.21)] at a somewhat slower rate than it yielded methane and ethylene by cracking 54... [Pg.45]

The reactions of alkenes and related compounds are grouped here into nine sections. The first five deal essentially with photoisomeriza-lion processes—geometrical isomerization about a carbon-carbon double bond, concerted (electrocydic) cyclization, concerted shifts (usually of hydrogen) along the ir-system, the di-jr-methane reaction. [Pg.40]

As you can see, the reaction formally amounts to the addition of methanal as H—CHO to the alkene double bond. Because one additional carbon atom is introduced as a formyl CHO group, the reaction often is called hydroformylation, although the older name, oxo reaction, is widely used. [Pg.723]


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See also in sourсe #XX -- [ Pg.88 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 ]




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