Metallophthalocyanines and

On account of their particularly extensive delocalized 7r-systems, MPs have received comparatively more attention for their cubic, as opposed to quadratic, NLO properties. From the viewpoint of practical applications, such complexes (and also metallophthalocyanines and other closely related compounds) are of major interest for OL due to their tendency to exhibit RSA behavior. These materials are particularly well suited in this regard because they often exhibit strongly absorbing, long-lived triplet excited states as well as reasonably wide transparency windows over the visible region of interest between the intense B- and Q-bands. 

The connection technique of molecules is important for the preparation of covalently bonded 2D arrays. As described in the previous section, the direct synthesis of metallophthalocyanine and metalloporphyrin can be achieved by the deposition... 

Gusev, A. Danilov. E.O. Rodgers. M.A.J. Association complexes between cationic metallophthalocyanines and anionic metalloporphyrins II Ultrafast studies of excited state dynamics. J. Phys. Chem.. A 2002. 106. 1993-2001. 

In the case of metallophthalocyanines and metalloporphyrins different ways to modified electrodes have been reported deposited onto electrodic surfaces complexes immobilized or incorporated in polymeric membranes as electropolymerized complexes , gas... 

Electropolymerized Metalloporphyrin, Metallophthalocyanine and Metal Schiff Base Complex Films Applications to Biomimetic Eiectrocataiysis and Bioeiectroanaiysis... 

Figure 8.3. Examples of metalloporphyrin, metallophthalocyanine and salen derivatives bearing electropolymerizable pyrrole or thiophene units.

Hutchinson, B., B. Spencer, R. Thompson, and P. Neill (1987). Metal— nitrogen stretching assignments in some metallophthalocyanines and -oxo-(Fephthalocyanine)2. Spectrochim. Acta A 43, 631. 

A number of rmsaturated polyazamacrocyclic complexes and their derivatives exhibit unusual properties, such as high metal-like conductivities or, conversely, semiconductor behaviour [90-96], Metallophthalocyanines and subphthalocyanines are promising non-linear optical materials for application in optoelectronic devices [97, 98] Porphyrins have been used in organic light-emitting diodes [99],... 

Z. Sun and H. Tachikawa, Enzyme-based bilayer conducting polymer electrodes consisting of poly-metallophthalocyanines and polypyrrole-glucose oxidase thin films. Anal. Chem. 64(10) II12 (1992). 

Mashazi P, Nombona N, Muchindu M, Vilakazi S (2012) Metallophthalocyanines and metalloporphyrins as electrocatalysts a case of hydrogen peroxide and glucose detectiotL J Porph Phthalo 16 742-753... 

Acar I, Bayrak R, Saka ET, Biyrkhoglu Z, Kanteldn H (2013) Novel metal-free, metallophthalocyanines and their quatemized derivatives synthesis, spectroscopic characterization and catal5rtic activity of cobalt phthalocyanine in 4-nitrophenol oxidation. Polyhedron 50 345-353... 

Hanack, M. and Lang, M., Conducting stacked metallophthalocyanines and related compounds, Adv. Mater., 6, 819, 1994. 

Quite a different situation occurs in the metallophthalocyanine and porphyrin complexes of l2 Here PVP is an active participant. The resistivity in the solid state is depressed at the molar ratios 1 1 1 1 1 1 (see Table II) by an order of magnitude in the cases of FePHTH and MgMTBP. The latter complex shows a dramatic further drop in activation energy. This effect is thought to be due to a ternary interaction, rather than an interaction between the PVP l2 (1 1) complex and the 1 1 metallo-organic I complex as shown by the increase in resistivity of MgMTBP I2 PVP = 1 2 1. 

Metallophthalocyanines and -naphthalocyanines have be used recently for the preparation of materials, which exhibit interesting semiconducting and nonlinear optical properties (1). In this report we concentrate on the electrical properties of phthalocyaninato and naphthalocyaninato transition metal compounds. A necessary condition for achieving good electrical conductivities in... 

Metallophthalocyanines and naphthalocyanines are less soluble in common organic solvents. However, soluble phthalocyanines R4PCM (R = r-Bu, Et, CH20Cj2H25> - CgHjy M = Fe, Ru) and RgPcM (R =... 

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