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Metal pseudo group 13 element

Summary Trimethyl- and triisopropyl-silyl diazomethane derivatives have been used for the synthesis of new types of diazo derivatives including those featuring a heavier main-group element or a transition metal directly bound to the diazo-carbon. They are also precursors to a variety of stable nitrilimines and carbodiimides, and stable pseudo-diazoalkenes and carbenes. (Phosphino)(silyl)carbenes have been used in the synthesis of new types of heterocycle including some stable four-7c-electron four-membered derivatives. [Pg.223]

Dye. J.L. Electrides From ID Heisenberg chains to 2D pseudo-metals. Inorg. Chem. 1997, 36. 3816-3826. Corbett. J.D. Exploratory synthesis in the solid state. Endless wonders. Inorg. Chein. 2000. 39. 5178-5191. Corbett, J.D. Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies. Stmct. Bond. 1997, 87. 157- 193. [Pg.339]

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See also in sourсe #XX -- [ Pg.183 ]



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Pseudo group 13 element

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