METAL PHOSPHORUS TRISULFIDES

ALKYLHALOPHOSPHINES, ALKYLPHOSPHINES tert-BUTYL PEROXOPHOSPHATE ESTERS iV-CHLORINATED PHOSPHORUS AMIDES HALOPHOSPHINES, METAL PHOSPHINATES METAL PHOSPHORUS TRISULFIDES NON-METAL OXIDES, NON-METAL SULFIDES PHOSPHINES, PHOSPHORUS ESTERS... [Pg.337]

See also ALKANETHIOLS, ALKENEBIS(SULFONIUM PERCHLORATES) allyl trifluo-ROMETHANESULFONATES, ARENEDIAZO ARYL SULFIDES BIS(ARENEDIAZO) sulfides, BIS(SULFURDIIMIDES DIAZONIUM SULFATES, DIAZONIUM SULFIDES AND DERIVATIVES METAL AMIDOSULFATES, METAL PHOSPHORUS TRISULFIDES METAL SULFATES, METAL SULFIDES, NON-METAL SULFIDES SULFONIC ACID ESTERS, SULFUR BLACK, SULFUR ESTERS THIOPHENOXIDES, XANTHATES ... [Pg.396]

Metal cyanides(and cyano complexes), 216 Metal derivatives of organofluorine compounds, 217 IV-Metal derivatives, 218 Metal dusts, 220 Metal fires, 222 Metal fulminates, 222 Metal halides, 222 Metal—halocarbon incidents, 225 Metal halogenates, 226 Metal hydrazides, 226 Metal hydrides, 226 Metal hypochlorites, 228 Metallurgical sample preparation, 228 Metal nitrates, 229 Metal nitrites, 231 Metal nitrophenoxides, 232 Metal non-metallides, 232 Metal oxalates, 233 Metal oxides, 234 Metal oxohalogenates, 236 Metal oxometallates, 236 Metal oxonon-metallates, 237 Metal perchlorates, 238 Metal peroxides, 239 Metal peroxomolybdates, 240 Metal phosphinates, 240 Metal phosphorus trisulfides, 240 Metal picramates, 241 Metal pnictides, 241 Metal polyhalohalogenates, 241 Metal pyruvate nitrophenylhydrazones, 241 Metals, 242 Metal salicylates, 243 Metal salts, 243 Metal sulfates, 244 Metal sulfides, 244 Metal thiocyanates, 246 Metathesis reactions, 246 Microwave oven heating, 246 Mild steel, 247 Milk powder, 248... [Pg.2639]

The metal phosphorus trisulfide phases, MPS3, form layered structures with M = Mg, V, Mn, Fe, Co, Ni, Zn, Pd, and Cd. All of the first transition series sulfides adopt the FePSs structure that is based on a cubic close-packed anion array with alternate layers of cation sites vacant. Within a layer, the cation sites are occupied by M + cations and P2 pairs, as shown in Figure 20. The two different types of octahedra are ordered so that each P2S6 octahedron is surrounded by six MSe octahedra and each MSe octahedron has three each of MSe and P2S6 neighbors. To emphasize the structural relationship to the dichalcogenides, the composition can be written M2/3(P2)i/3S2. [Pg.1784]

The first-row transition metal phosphorus trisulfides all form a common monoclinic structure (C2/m) based on the CdCl2 type (Figure 64). This consists of a cubic close-packed anion array with alternate layers of cation sites vacant. Within a layer, two-thirds of the cation sites are occupied by cations and one-third by P2 pairs. The structure is related to the CdCl2 lattice, since the ions and the center of the P-P pairs occupy the Cd positions and the sulfur ions occupy the chloride positions. [Pg.821]