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Metal fluorinating agent

The nitrile group is probably the functional group that is most stable to fluorination by transition metal fluorinating agents. [Pg.670]

Use Sand casting of aluminum and magnesium, electrochemical processes, oxidation inhibitor, fluxes for nonferrous metals, fluorinating agent. [Pg.1144]

The only important compound is the paramagnetic silver(II) fluoride, AgFj, prepared by fluorination of the metal it is used as a convenient fluorinating agent. [Pg.427]

Molten alkali metals, elemental fluorine, strong fluorinating agents... [Pg.58]

The chemical reactions of XY can be conveniently classified as (a) halogenation reactions, (b) donor-acceptor interactions and (c) use as solvent systems. Reactions frequently parallel those of the parent halogens but with subtle and revealing differences. CIF is an effective fluorinating agent (p. 820) and will react with many metals and non-metals either at room temperature or above, converting them to fluorides and liberating chlorine, e.g. ... [Pg.826]

The xenon fluorides are used as powerful fluorinating agents (reagents for attaching fluorine atoms to other substances). The tetrafluoride will even fluori-nate platinum metal ... [Pg.766]

Reaction of HC=NH+ salts of [AsFft] or RpCsN adducts of AsF5 with KrFj in nonaqueous solvents lead to salts characterized as [HCsN—Kr —F]+[AsFfi] and [RFC=N — Kr—F]+[AsFfi] (RF = CF, C2Fj. n-C F7). Krypton fluoride has proven extremely useful as a fluorinating agent It is 50 kJ mol-1 more exothermic than fluorine. F, It may be used to raise metals to unusual oxidation states 21... [Pg.430]

Kinetics of the transformations of the N-F class of fluorinating agents in water, acetonitrile, alcohols, and aqueous solutions of alkali metal hydroxides have been studied.159 Other kinetic studies include die reactions of triphenylphosphine with 3-methoxy- or 3-acctoxy-4,4,5,5-tetrasubstitutcd-1,2-dioxolanes,160 the reactions of 2-amino-5-chlorobenzophenone witii HC1 in MeOH-H20 (die aspect of nucleophilic aliphatic substitution lies in certain products arising from attack of AH2 on CH3OH there are six products in all, and rate constants are evaluated for die formation of each of them),161 and the hydrolysis of derivatives of diazidophenyhnethane.162... [Pg.322]

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See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.3 , Pg.5 , Pg.12 ]



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Fluorinating agents

Metal agents

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