Metal atoms reactions with

To conclude, we shall mention some metal-atom reactions with boranes (172) and carboranes (173). When cobalt atoms reacted with pentaboraneO) and cyclopentadiene, a number of new metalloborane clusters were formed (172), two of which were 65115003(17-05115)3 and cyclopentyl-B5H40o2(i7-05H5)3. Possible structures for the former are shown in Fig. 42. The reaction of cyclopentadiene, pentaboraneO), and 2-butyne with cobalt atoms yielded the metallocarborane species illustrated in Fig. 43 (173). 

Aspects of the apparatus for the synthesis using metal atoms are described. The reactions of the atoms of rhenium, tungsten, and osmium with hydrocarbons including alkanes are described. It is shown that metal atom reactions with alkanes can give isolable organometallic compounds including l-alkylidene compounds. 

Metal Atom Reactions with Polyimides, A Critique of Model Compound Studies... 

Metal-Atom Reactions with Water and its Isoelectronlc Analogs... 

On Pt, OH adsorbs on an atop site. Therefore, its interactions with NH3, NH2 and NH with OH in the transition state do not share binding to the same metal atom. Reactions with adsorbed OH to form H2O lower the activation energies for all three of these cases. 

Recently, researchers studying the kinetics of metal atom reactions with small gas molecules measured a rate constant for the gas-phase reaction of... 

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