Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Meso stereoisomer

Fischer projection formulas can help us identify meso forms Of the three stereoisomeric 2 3 butanediols notice that only in the meso stereoisomer does a dashed line through the center of the Fischer projection divide the molecule into two mirror image halves... [Pg.304]

A meso stereoisomer is possible for one of the following com pounds Which one ... [Pg.304]

Merrifield method See solid phase peptide synthesis Meso stereoisomer (Section 7 11) An achiral molecule that has chirality centers The most common kind of meso com pound IS a molecule with two chirality centers and a plane of symmetry... [Pg.1288]

Stereoselective synthesis of pseudo C2-symmetrical 1,3-dibenzyldiamino alcohol (S,S) (323) a core unit of HIV protease inhibitors, and the two meso-stereoisomers (323a) and (323b) was achieved by stereocontrolled addition of benzylmagnesium chloride to nitrones (63a) and (63b) (Scheme 2.137). The yield of (S,S)-(323), based on N-Boc-L-phenylalaninal, accounts for 23% (Scheme 2.137) (211). [Pg.243]

A C2-symmetric ansa metallocene is a racemic mixture of an enantiomeric pair—an example is rac-(dimethylsilyl)bis(l-indenyl)zirconium dichloride (XXXIV), abbreviated as rac-(CH3)2SiInd2ZrCl2. The enantiomers are designated as (R, R) and (S, S) to describe the two coordination sites in each enantiomer. Actually, the synthesis of a C2 ansa metallocene usually produces a mixture of the racemic pair plus the meso compound (R, S). The meso compound, which is a diastereomer of the racemic pair, can be separated from the racemic mixture by physical techniques such as recrystallization. The meso stereoisomer possesses Cs symmetry, and its stereoselectivity is very different from that of the enantiomeric pair (Sec. 8-5a-3). [Pg.669]

Complexation with racemic 2,3-di(4-aminophenyl)butane (L) gave Ag(L)3N03, which was claimed to be six-coordinate with the silver bound to the six donor atoms. By comparison, the meso stereoisomer gave only a 1 1 complex AgN03. [Pg.782]

Meso stereoisomer (achiral) plane of symmetry indicated with dashed line... [Pg.787]

In favorable circumstances, active (or dl) and meso stereoisomers may be distinguished directly an acyclic (84) and a cyclic (85) example are shown in Fig. 34. In both cases the methylene protons Hc in the active forms are related by a C2 axis and therefore homotopic and isochronous whereas the corresponding protons HA and Hb in the meso forms are not related by either C2 or a and are therefore diastereotopic and anisochronous. The situation is not altered when the dl form rather than an active isomer is compared with the meso form the (internally homotopic) methylene protons of the two enantiomers are externally enantiotopic and so remain isochronous. [Pg.30]

The meso stereoisomer of tartaric acid is achiral, and possesses two self-cancelling stereogenic centres of opposite configuration. [Pg.39]

As the number of stereocenters in a molecule increases, the number of possible diastereomers increases. A molecule with four dissimilar stereocenters, for example, can exist as one of sixteen stereoisomers. Of these sixteen stereoisomers there are four pairs of enantiomers, and the remaining four pairs are diastereomers. Molecules with configurational diastereomers also arise from many systems other than those with stereocenters. One of the most common examples is a double bond that is substituted in such a way that diastereomers exist. Any combination of two or more molecular features that give rise to stereoisomers will always produce diastereomers, whereas sources of chirality are needed to produce enantiomers. Because stereochemistry can have a high impact on molecular properties, diastereomers generally have easily discernable differences in their physical and chemical behaviors. Some molecules possess greater than or equal to two tetrahedral stereocenters and are nonetheless achiral. These are called meso stereoisomers. These occur when the internal symmetry of the molecule makes it superimposable on its mirror image. [Pg.250]

Fischer esterification. See Esterification Esters Fischer projection formulas, 271-272, 278, 280, 292, 595 a-amino acids, 1056, 1103 carbohydrates, 973-974, 1007 of meso stereoisomer, 280 tartaric acids, 286... [Pg.1226]


See other pages where Meso stereoisomer is mentioned: [Pg.1226]    [Pg.304]    [Pg.1226]    [Pg.400]    [Pg.126]    [Pg.311]    [Pg.1233]    [Pg.164]    [Pg.131]    [Pg.78]    [Pg.219]    [Pg.234]    [Pg.201]    [Pg.27]    [Pg.329]    [Pg.1141]    [Pg.310]    [Pg.1164]    [Pg.1232]    [Pg.1413]   
See also in sourсe #XX -- [ Pg.303 , Pg.304 ]

See also in sourсe #XX -- [ Pg.303 , Pg.304 ]

See also in sourсe #XX -- [ Pg.303 , Pg.304 ]

See also in sourсe #XX -- [ Pg.279 , Pg.280 , Pg.281 ]

See also in sourсe #XX -- [ Pg.301 ]

See also in sourсe #XX -- [ Pg.284 , Pg.285 ]




SEARCH



Fischer projection formulas of meso stereoisomer

Fischer projections meso stereoisomer

Meso Compounds the Stereoisomers of Tartaric Acid

Stereoisomer

Stereoisomers

Stereoisomers, meso

Stereoisomers, meso

Stereoisomers, meso compounds

Stereoisomers, meso radicals

© 2024 chempedia.info