Mercury complexes amides

The organo-corrinoids show similar behavior, but also additional complications. Rate constants have been determined 84) for the attack of mercury(II) acetate on various organocobalt cobinamides (X = H2O or absent) and cobalamins (X = 5,6-dimethylbenziminazole). The first complication, which has to be born in mind when comparing the cobinamides with the cobalamins or DMG complexes, is that the organocobin-amides are partly (R = vinyl and methyl) or wholly (R = Et, -Pr, t-Pr,... 

Formation of the 1 1 complexes with zinc and cadmium has been studied in aqueous solution, and the complexes are more stable than the corresponding 1 1 adducts with bipy 245). Ternary mercury(II)-hydroxo-terpy complexes are active catalysts for hydrolysis of esters and amides 477). 

Divalent metal silylamide complexes are easily obtained from the interaction of the corresponding REM with mercury amide in DME medium at room temperature [15] ... 

---