Medium Effects on Chlorine Shielding Values

Medium effects on chlorine shifts have not been reported in the literature. This is most likely due to the experimental difficulties in determining chlorine NMR shifts from covalent compounds even for neat 

Fourier transform techniques at 30 C give an upfield C1 shift on dilution of TiCl in n-hexane while dilution in CH2I2 is accompanied by a downfield shift (Table 3.5). The directions of these dilution 

Solution Chlorine chemical shift relative to neat TiCl4. Data are given in ppm with an upfield shift given as positive. Experimental method 

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