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Mechanical Photoisomerizable Monolayers

EUGENH KATZ.ANDREW N. SHIPWAY, AND ITAMAR WllLNER [Pg.244]

5 RECOGNITION PHENOMENA AT SURFACES USING PHOTOISOMERIZABLE GUEST OR HOST COMPONENTS [Pg.246]

1 Affinity Interactions at Interlaces Using Soluble PhottHsomerizable Guest Components [Pg.246]

2 The interaction of a solution-state species with a receptor-functionalized interface mar be controlled by the isomerization of the free componenc [Pg.246]

An interesting example of a system whose components become mechanically bound upon surface immobilization is rotaxane trans-21 (Fig. 13.24), consisting of a ferrocene-functionalized /3-cyclodextrin (fi-CD) macrocycle threaded on a molecule containing a photoisomerizable azobenzene unity and a long alkyl chain.33 A monolayer of trans-21 was self-assembled on a gold electrode. Therefore, the ring... [Pg.404]

See other pages where Mechanical Photoisomerizable Monolayers is mentioned: [Pg.219] [Pg.243] [Pg.219] [Pg.243] [Pg.568] [Pg.219] [Pg.243] [Pg.219] [Pg.243] [Pg.568] [Pg.376] [Pg.514] [Pg.258] [Pg.258] [Pg.674]

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Monolayers mechanism

Photoisomerizables