McCarty Pyrolysis Kinetics

Table 4-206 Pyrolysis kinetics of bitumen B80 according to McCarty and Green. Experiments with Simultaneous Thermal Analyzer...

Table 4-207 Pyrolysis kinetics according to McCarty and Green.

Fig. 3-65 Reaction Kinetics according to McCarty and Green [3-24] Pyrolysis of CaCjO HjO Heating Rate ]3 10 K/min...

Fig. 4-206 Pyrolysis of Bitumen B80 STA Diagram TGA Heating Rate 10 K/min Atmosphere Argon 30 + 20 cm /min Kinetics according McCarty and Green Integration Limits 250 °C and 520 °C...

The application of thermoanalytical methods to the investigation of the kinetics of pyrolysis and oxidation processes of heavy petroleum components representing multi-component systems proved to be successful. Whereas the ASTM E 698-79 and the Flynn and Wall methods can be applied relatively uncritically, the interpretation of the data from the McCarty and Green method requires a solid knowledge of the thermal and oxidative behavior of the samples. The attempt to use the evaluation according to Borchardt and Daniels proved not to be successful for pyrolysis nor for oxidation reactions. Most of the... 

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