Mass fluid-solid microstructured

Other low-temperature studies have been motivated by the desire to characterize and understand processes occurring in unusual media. For example, the use of liquid ammonia [8-10] and liquid sulfur dioxide [11-13] naturally requires reduced temperatures unless high pressures are used, as is done for electrochemistry in supercritical fluids [14]. Frozen media are interesting systems in terms of mass transport phenomena and microstructural effects. Examples include glasses of acetonitrile and acetone [15], frozen dimethyl sulfoxide solutions [16,17], and the solid electrolyte HC104 5.5 H20 [18-20]. 

The above-described mixers are essentially low-viscosity devices. In many operations where the viscosity is high, when dealing with concentrated multiphase gas-liquid-solid binary or tertiary systems, or when liquid-to-solid phase transformation occurs during mixing, novel equipment designs are needed to intensify the heat/mass transfer processes. The multiphase fluids also represent an important class of materials that have microstructure developed during processing and subsequently frozen-in, ready for use as a product. To deliver certain desired functions, the control of microstructure in the product is important. This microstructure is developed in most cases by the interaction between the fluid flow and the fluid microstructure hence, uniformity of the flow field is important. 

When fluids can seep through pores, interacting mechanically with the solid skeleton, the material is composed of more than one constituent thus we need to use a mixture theory in which we could clearly make out each part filled by different constituents on a scale which is rather large in comparison with molecular dimensions so we put forward a new continuum theory of an immiscible mixture consisting both of a continuum with ellipsoidal microstructure (the porous elastic solid) and of two classical media (see, also, the conservative case examined by Giovine (2000)). In accordance with Biot (1956), we consider virtual mass effects due to diffusion we also introduce the microinertia associated with the rates of change of the constituents local densities, as well as the one due to the deformation of the pores close to their boundaries. 

In this chapter, different types of microstructures and their applications are presented. The results presented herein clearly indicate that MSR and structured catalysts offer superior mass transfer performance at lower energy dissipation in comparison to conventional equipment Therefore, the influence of concentration gradients between fluid and solid and within the porous catalyst can be effectively diminished or even suppressed, leading to high product selectivity and yield. 

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