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Mass balances process analysis procedure

For process analysis including energy balances, the same procedure defined for mass balances is followed. The only change is that the source of equations, described in item 3 of the procedure, now includes the energy balance equation as well as the definition of different energy terms. Again, this procedure will be illustrated by example. [Pg.16]

Those based on strictly empirical descriptions Mathematical models based on physical and cnemical laws (e.g., mass and energy balances, thermodynamics, chemical reaction kinetics) are frequently employed in optimization applications. These models are conceptually attractive because a general model for any system size can be developed before the system is constructed. On the other hand, an empirical model can be devised that simply correlates input/output data without any physiochemical analysis of the process. For these models, optimization is often used to fit a model to process data, using a procedure called parameter estimation. The well-known least squares curve-fitting procedure is based on optimization theory, assuming that the model parameters are contained linearly in the model. One example is the yield matrix, where the percentage yield of each product in a unit operation is estimated for each feed component... [Pg.33]

The solution to the problem is obtained by solving mass and energy balances to yield the quantity and state (i.e., composition, temperature, pressure) of all the streams and the utility requirements. Additional parameters for the process equipment, sufficient so that stream specifications are met and the cost of the equipment can be estimated, are calculated. The cost of equipment, raw materials, and utilities is estimated and an economic analysis is carried out. Methods of cost estimation and economic analysis are presented later in this text. This entire procedure may be repeated many times to examine modifications of the process flow sheet or to find optimal values of key process variables. Computer software can greatly simplify these repetitive calculations for the engineer. But even without the need for repetition, the software may simplify the calculations and provide detail and accuracy that would have been impossible otherwise. [Pg.126]


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