Martin operational problems

The rivers play a major role in the transfert of carbon and mineral nutrients from land to the sea and influence significantly the biogeochemical processes operating in coastal waters. Quantification of the material transport, both in the dissolved and particulate forms, has been attempted by several authors in the past (Clarke, 1924 Holeman, 1968 Garrels McKenzie, 1971 Martin et al., 1980 Meybeck, 1982 Milliman Meade, 1983). Depending on the type of sampling techniques and methods of calculations employed there are differences in the reported fluxes. A major problem in such calculations is the paucity of reliable data from some of the major rivers of the world especially of Asia (see e.g. Milliman Meade, 1983). Additionally the difficulty of obtaining representative samples from the rivers will adversely affect flux calculations. Most of the inferences drawn on the nature and transport of riverine materials rest on data collected randomly - at different points in time and space. Seasonal variations in the transport of materials are very common in some of the major world rivers, and in some cases more than 60 % of the material transport occurs within a very short period of time. Furthermore, available data are not always comparable since the analytical techniques used differ from river to river. 

Martin et al. published a paper on the theoretical limits of HPLC which is well worth reading.They used relatively simple mathematics to calculate pressure-optimized columns for which the length L, particle size and flow rate u of the mobile phase were selected such that a minimum pressure Ap is required to solve a separation problem. It has been shown that these optimized colunms are operated at their van Deemter curve minima. Some astonishing facts have emerged from the study, provided that the chromatography is performed on well packed columns (reduced plate height h = 2-3 see Section 8.5). 

Gas density balance. The gas density balance, designed by Martin and James, is a universal detector which appears to be ideal for GC [84-86]. However, problems of sensitivity and stability compared to ionisation detectors have prevented its more widespread use. Interest has been maintained since direct determination of molecular weight is achieved. The operation depends on detecting minute gas flows in what amounts to a supersensitive anemometer/TCD (Figure 5.25). 

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