Manganese complexes alkyl phosphines

Manganese(tl) complexes,, 3, 9-82 acctylacetonates, 48 acetylides, 14 alcohols, 37 alkoxides, 37 alkyl phosphines, 13 alkyls, 12 amides, 15, 16 amine oxides, 39 amines, 16 amino acids, 43, 62 sulfur containing, 70 ammines, 15 antimony ligands, 31-34 arsenates, 4,5, 46 arsenic ligands, 31-34 arsenic oxides, 39 aryls, 12, 14 azides, 22 binary alkyls, 13 bipyridyl, 24, 25 anions, 25... 

Alkyl- and aryl-cobalt tetracarbonyls also react readily with phosphines forming acyl derivatives RCOCo(CO)3PR 3. Phosphite ligands are found to replace carbon monoxides successively forming RCOCo(CO)2L2 [193]. The replacement of two carbon monoxide ligands by phosphites under conditions where phosphine ligands will only replace one carbon monoxide, is therefore found for both cobalt and manganese complexes. Both... 

Phosphine complexes with alkyl ligands are discussed in the chapter Manganese Organometallic Chemistry. 

---